[μ-Bis(trimethyl­silyl)amido]bis­[μ-N,N-dimethyl-N′,N′′-bis­(trimethyl­silyl)guanidinato]-triangulo-tricopper(I)

The title compound, [Cu(3)(C(6)H(18)NSi(2))(C(9)H(24)N(3)Si(2))(2)], is a trinuclear Cu(I) complex. A crystallographic twofold axis passes through one Cu(I) atom and the N atom of the bis­(trimethyl­silyl)amide ligand that bridges between the other two Cu(I) atoms. The Cu—Cu bonds bridged by the gua...

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Detalles Bibliográficos
Autores principales: Guo, Donglong, Qiao, Xiaoli, Tong, Hong-Bo, Zhou, Meisu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968876/
https://www.ncbi.nlm.nih.gov/pubmed/21582350
http://dx.doi.org/10.1107/S1600536809008745
Descripción
Sumario:The title compound, [Cu(3)(C(6)H(18)NSi(2))(C(9)H(24)N(3)Si(2))(2)], is a trinuclear Cu(I) complex. A crystallographic twofold axis passes through one Cu(I) atom and the N atom of the bis­(trimethyl­silyl)amide ligand that bridges between the other two Cu(I) atoms. The Cu—Cu bonds bridged by the guanadinate ligands [2.7913 (9) Å] are slightly longer than the Cu—Cu bond bridged by the bis­(trimethyl­silyl)amide ligand [2.6405 (11) Å].

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