[μ-Bis(trimethyl­silyl)amido]bis­[μ-N,N-dimethyl-N′,N′′-bis­(trimethyl­silyl)guanidinato]-triangulo-tricopper(I)

The title compound, [Cu(3)(C(6)H(18)NSi(2))(C(9)H(24)N(3)Si(2))(2)], is a trinuclear Cu(I) complex. A crystallographic twofold axis passes through one Cu(I) atom and the N atom of the bis­(trimethyl­silyl)amide ligand that bridges between the other two Cu(I) atoms. The Cu—Cu bonds bridged by the gua...

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Detalles Bibliográficos
Autores principales: Guo, Donglong, Qiao, Xiaoli, Tong, Hong-Bo, Zhou, Meisu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968876/
https://www.ncbi.nlm.nih.gov/pubmed/21582350
http://dx.doi.org/10.1107/S1600536809008745
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author Guo, Donglong
Qiao, Xiaoli
Tong, Hong-Bo
Zhou, Meisu
author_facet Guo, Donglong
Qiao, Xiaoli
Tong, Hong-Bo
Zhou, Meisu
author_sort Guo, Donglong
collection PubMed
description The title compound, [Cu(3)(C(6)H(18)NSi(2))(C(9)H(24)N(3)Si(2))(2)], is a trinuclear Cu(I) complex. A crystallographic twofold axis passes through one Cu(I) atom and the N atom of the bis­(trimethyl­silyl)amide ligand that bridges between the other two Cu(I) atoms. The Cu—Cu bonds bridged by the guanadinate ligands [2.7913 (9) Å] are slightly longer than the Cu—Cu bond bridged by the bis­(trimethyl­silyl)amide ligand [2.6405 (11) Å].
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spelling pubmed-29688762010-12-30 [μ-Bis(trimethyl­silyl)amido]bis­[μ-N,N-dimethyl-N′,N′′-bis­(trimethyl­silyl)guanidinato]-triangulo-tricopper(I) Guo, Donglong Qiao, Xiaoli Tong, Hong-Bo Zhou, Meisu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(3)(C(6)H(18)NSi(2))(C(9)H(24)N(3)Si(2))(2)], is a trinuclear Cu(I) complex. A crystallographic twofold axis passes through one Cu(I) atom and the N atom of the bis­(trimethyl­silyl)amide ligand that bridges between the other two Cu(I) atoms. The Cu—Cu bonds bridged by the guanadinate ligands [2.7913 (9) Å] are slightly longer than the Cu—Cu bond bridged by the bis­(trimethyl­silyl)amide ligand [2.6405 (11) Å]. International Union of Crystallography 2009-03-14 /pmc/articles/PMC2968876/ /pubmed/21582350 http://dx.doi.org/10.1107/S1600536809008745 Text en © Guo et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Donglong
Qiao, Xiaoli
Tong, Hong-Bo
Zhou, Meisu
[μ-Bis(trimethyl­silyl)amido]bis­[μ-N,N-dimethyl-N′,N′′-bis­(trimethyl­silyl)guanidinato]-triangulo-tricopper(I)
title [μ-Bis(trimethyl­silyl)amido]bis­[μ-N,N-dimethyl-N′,N′′-bis­(trimethyl­silyl)guanidinato]-triangulo-tricopper(I)
title_full [μ-Bis(trimethyl­silyl)amido]bis­[μ-N,N-dimethyl-N′,N′′-bis­(trimethyl­silyl)guanidinato]-triangulo-tricopper(I)
title_fullStr [μ-Bis(trimethyl­silyl)amido]bis­[μ-N,N-dimethyl-N′,N′′-bis­(trimethyl­silyl)guanidinato]-triangulo-tricopper(I)
title_full_unstemmed [μ-Bis(trimethyl­silyl)amido]bis­[μ-N,N-dimethyl-N′,N′′-bis­(trimethyl­silyl)guanidinato]-triangulo-tricopper(I)
title_short [μ-Bis(trimethyl­silyl)amido]bis­[μ-N,N-dimethyl-N′,N′′-bis­(trimethyl­silyl)guanidinato]-triangulo-tricopper(I)
title_sort [μ-bis(trimethyl­silyl)amido]bis­[μ-n,n-dimethyl-n′,n′′-bis­(trimethyl­silyl)guanidinato]-triangulo-tricopper(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968876/
https://www.ncbi.nlm.nih.gov/pubmed/21582350
http://dx.doi.org/10.1107/S1600536809008745
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