Isopropyl N-[1′-(methoxy­carbon­yl)ferro­cen­yl]carbamate–ethyl N-[1′-(methoxy­carbon­yl)ferrocen­yl]carbamate (0.6/0.4)

Herein we report the crystal structure and synthesis of two cocrystallized complexes, [Fe(C(7)H(7)O(2))(C(9)H(12)NO(2))](0.6)[Fe(C(7)H(7)O(2))(C(8)H(10)NO(2))](0.4). The molecules crystallize as layers in the bc plane with van der Waals interactions allowing the alkyl chains to interact and the ferr...

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Detalles Bibliográficos
Autores principales: Lataifeh, Anas, Kraatz, Heinz-Bernhard, Jennings, Michael C.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968887/
https://www.ncbi.nlm.nih.gov/pubmed/21582347
http://dx.doi.org/10.1107/S1600536809008204
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author Lataifeh, Anas
Kraatz, Heinz-Bernhard
Jennings, Michael C.
author_facet Lataifeh, Anas
Kraatz, Heinz-Bernhard
Jennings, Michael C.
author_sort Lataifeh, Anas
collection PubMed
description Herein we report the crystal structure and synthesis of two cocrystallized complexes, [Fe(C(7)H(7)O(2))(C(9)H(12)NO(2))](0.6)[Fe(C(7)H(7)O(2))(C(8)H(10)NO(2))](0.4). The molecules crystallize as layers in the bc plane with van der Waals interactions allowing the alkyl chains to interact and the ferrocene units to form a herringbone pattern up the c axis. Every second layer is linked via N—H⋯O hydrogen bonding.The two complexes were modelled as disordered in a ratio of 0.60:0.40.
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spelling pubmed-29688872010-12-30 Isopropyl N-[1′-(methoxy­carbon­yl)ferro­cen­yl]carbamate–ethyl N-[1′-(methoxy­carbon­yl)ferrocen­yl]carbamate (0.6/0.4) Lataifeh, Anas Kraatz, Heinz-Bernhard Jennings, Michael C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Herein we report the crystal structure and synthesis of two cocrystallized complexes, [Fe(C(7)H(7)O(2))(C(9)H(12)NO(2))](0.6)[Fe(C(7)H(7)O(2))(C(8)H(10)NO(2))](0.4). The molecules crystallize as layers in the bc plane with van der Waals interactions allowing the alkyl chains to interact and the ferrocene units to form a herringbone pattern up the c axis. Every second layer is linked via N—H⋯O hydrogen bonding.The two complexes were modelled as disordered in a ratio of 0.60:0.40. International Union of Crystallography 2009-03-14 /pmc/articles/PMC2968887/ /pubmed/21582347 http://dx.doi.org/10.1107/S1600536809008204 Text en © Lataifeh et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lataifeh, Anas
Kraatz, Heinz-Bernhard
Jennings, Michael C.
Isopropyl N-[1′-(methoxy­carbon­yl)ferro­cen­yl]carbamate–ethyl N-[1′-(methoxy­carbon­yl)ferrocen­yl]carbamate (0.6/0.4)
title Isopropyl N-[1′-(methoxy­carbon­yl)ferro­cen­yl]carbamate–ethyl N-[1′-(methoxy­carbon­yl)ferrocen­yl]carbamate (0.6/0.4)
title_full Isopropyl N-[1′-(methoxy­carbon­yl)ferro­cen­yl]carbamate–ethyl N-[1′-(methoxy­carbon­yl)ferrocen­yl]carbamate (0.6/0.4)
title_fullStr Isopropyl N-[1′-(methoxy­carbon­yl)ferro­cen­yl]carbamate–ethyl N-[1′-(methoxy­carbon­yl)ferrocen­yl]carbamate (0.6/0.4)
title_full_unstemmed Isopropyl N-[1′-(methoxy­carbon­yl)ferro­cen­yl]carbamate–ethyl N-[1′-(methoxy­carbon­yl)ferrocen­yl]carbamate (0.6/0.4)
title_short Isopropyl N-[1′-(methoxy­carbon­yl)ferro­cen­yl]carbamate–ethyl N-[1′-(methoxy­carbon­yl)ferrocen­yl]carbamate (0.6/0.4)
title_sort isopropyl n-[1′-(methoxy­carbon­yl)ferro­cen­yl]carbamate–ethyl n-[1′-(methoxy­carbon­yl)ferrocen­yl]carbamate (0.6/0.4)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968887/
https://www.ncbi.nlm.nih.gov/pubmed/21582347
http://dx.doi.org/10.1107/S1600536809008204
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AT jenningsmichaelc isopropyln1methoxycarbonylferrocenylcarbamateethyln1methoxycarbonylferrocenylcarbamate0604

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