[Cu(2)(HF(2))(H(2)O)(8)][FeF(6)]·2H(2)O

The title compound, octaaqua­(hydrogenfluorido)dicopper(II) hexa­fluoridoferrate(III) dihydrate, was synthesized under hydro­thermal conditions. The Cu atom is coordinated by one F and five O atoms within a highly distorted octa­hedron, forming dimeric [Cu(2)(H(2)O)(8)HF(2)](3+) units by edge sharin...

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Detalles Bibliográficos
Autores principales: Le Bail, Armel, Mercier, Anne-Marie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968889/
https://www.ncbi.nlm.nih.gov/pubmed/21582307
http://dx.doi.org/10.1107/S1600536809006874
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author Le Bail, Armel
Mercier, Anne-Marie
author_facet Le Bail, Armel
Mercier, Anne-Marie
author_sort Le Bail, Armel
collection PubMed
description The title compound, octaaqua­(hydrogenfluorido)dicopper(II) hexa­fluoridoferrate(III) dihydrate, was synthesized under hydro­thermal conditions. The Cu atom is coordinated by one F and five O atoms within a highly distorted octa­hedron, forming dimeric [Cu(2)(H(2)O)(8)HF(2)](3+) units by edge sharing. These units are hydrogen bonded to [FeF(6)](3−) anions and to an inter­stitial water mol­ecule. The former feature Fe(3+) on a special position ([Image: see text]). The dimeric copper units are linked to adjacent dimers by F—H⋯F hydrogen bonds. Additional O—H⋯O and O—H⋯F hydrogen bonds help to consolidate the crystal packing.
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spelling pubmed-29688892010-12-30 [Cu(2)(HF(2))(H(2)O)(8)][FeF(6)]·2H(2)O Le Bail, Armel Mercier, Anne-Marie Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, octaaqua­(hydrogenfluorido)dicopper(II) hexa­fluoridoferrate(III) dihydrate, was synthesized under hydro­thermal conditions. The Cu atom is coordinated by one F and five O atoms within a highly distorted octa­hedron, forming dimeric [Cu(2)(H(2)O)(8)HF(2)](3+) units by edge sharing. These units are hydrogen bonded to [FeF(6)](3−) anions and to an inter­stitial water mol­ecule. The former feature Fe(3+) on a special position ([Image: see text]). The dimeric copper units are linked to adjacent dimers by F—H⋯F hydrogen bonds. Additional O—H⋯O and O—H⋯F hydrogen bonds help to consolidate the crystal packing. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2968889/ /pubmed/21582307 http://dx.doi.org/10.1107/S1600536809006874 Text en © Bail and Mercier 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Le Bail, Armel
Mercier, Anne-Marie
[Cu(2)(HF(2))(H(2)O)(8)][FeF(6)]·2H(2)O
title [Cu(2)(HF(2))(H(2)O)(8)][FeF(6)]·2H(2)O
title_full [Cu(2)(HF(2))(H(2)O)(8)][FeF(6)]·2H(2)O
title_fullStr [Cu(2)(HF(2))(H(2)O)(8)][FeF(6)]·2H(2)O
title_full_unstemmed [Cu(2)(HF(2))(H(2)O)(8)][FeF(6)]·2H(2)O
title_short [Cu(2)(HF(2))(H(2)O)(8)][FeF(6)]·2H(2)O
title_sort [cu(2)(hf(2))(h(2)o)(8)][fef(6)]·2h(2)o
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968889/
https://www.ncbi.nlm.nih.gov/pubmed/21582307
http://dx.doi.org/10.1107/S1600536809006874
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AT mercierannemarie cu2hf2h2o8fef62h2o

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