2(4),4,8-Trioxa-2(1)-aza-1,3,6(1,2)-tri­benzena-2(2,3)-bicyclo­[3.3.0]octa­na­cyclo­octa­phane

The crystal structure of the title compound, C(26)H(25)NO(3), was determined as part of an investigation of host–guest and electron donor–acceptor complexes. The oxazole and the pyrrole rings both adopt envelope conformations. The dihedral angle between the two benzene rings directly linked to the o...

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Detalles Bibliográficos
Autores principales: Seshadri, P. R., Balakrishnan, B., Ilangovan, K., Purushothaman, S., Raghunathan, R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968892/
https://www.ncbi.nlm.nih.gov/pubmed/21582414
http://dx.doi.org/10.1107/S160053680900720X
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author Seshadri, P. R.
Balakrishnan, B.
Ilangovan, K.
Purushothaman, S.
Raghunathan, R.
author_facet Seshadri, P. R.
Balakrishnan, B.
Ilangovan, K.
Purushothaman, S.
Raghunathan, R.
author_sort Seshadri, P. R.
collection PubMed
description The crystal structure of the title compound, C(26)H(25)NO(3), was determined as part of an investigation of host–guest and electron donor–acceptor complexes. The oxazole and the pyrrole rings both adopt envelope conformations. The dihedral angle between the two benzene rings directly linked to the oxazole ring is 49.5 (1)°. The crystal structure is stabilized by a C—H⋯π inter­action.
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spelling pubmed-29688922010-12-30 2(4),4,8-Trioxa-2(1)-aza-1,3,6(1,2)-tri­benzena-2(2,3)-bicyclo­[3.3.0]octa­na­cyclo­octa­phane Seshadri, P. R. Balakrishnan, B. Ilangovan, K. Purushothaman, S. Raghunathan, R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound, C(26)H(25)NO(3), was determined as part of an investigation of host–guest and electron donor–acceptor complexes. The oxazole and the pyrrole rings both adopt envelope conformations. The dihedral angle between the two benzene rings directly linked to the oxazole ring is 49.5 (1)°. The crystal structure is stabilized by a C—H⋯π inter­action. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2968892/ /pubmed/21582414 http://dx.doi.org/10.1107/S160053680900720X Text en © Seshadri et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Seshadri, P. R.
Balakrishnan, B.
Ilangovan, K.
Purushothaman, S.
Raghunathan, R.
2(4),4,8-Trioxa-2(1)-aza-1,3,6(1,2)-tri­benzena-2(2,3)-bicyclo­[3.3.0]octa­na­cyclo­octa­phane
title 2(4),4,8-Trioxa-2(1)-aza-1,3,6(1,2)-tri­benzena-2(2,3)-bicyclo­[3.3.0]octa­na­cyclo­octa­phane
title_full 2(4),4,8-Trioxa-2(1)-aza-1,3,6(1,2)-tri­benzena-2(2,3)-bicyclo­[3.3.0]octa­na­cyclo­octa­phane
title_fullStr 2(4),4,8-Trioxa-2(1)-aza-1,3,6(1,2)-tri­benzena-2(2,3)-bicyclo­[3.3.0]octa­na­cyclo­octa­phane
title_full_unstemmed 2(4),4,8-Trioxa-2(1)-aza-1,3,6(1,2)-tri­benzena-2(2,3)-bicyclo­[3.3.0]octa­na­cyclo­octa­phane
title_short 2(4),4,8-Trioxa-2(1)-aza-1,3,6(1,2)-tri­benzena-2(2,3)-bicyclo­[3.3.0]octa­na­cyclo­octa­phane
title_sort 2(4),4,8-trioxa-2(1)-aza-1,3,6(1,2)-tri­benzena-2(2,3)-bicyclo­[3.3.0]octa­na­cyclo­octa­phane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968892/
https://www.ncbi.nlm.nih.gov/pubmed/21582414
http://dx.doi.org/10.1107/S160053680900720X
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AT ilangovank 2448trioxa21aza13612tribenzena223bicyclo330octanacyclooctaphane
AT purushothamans 2448trioxa21aza13612tribenzena223bicyclo330octanacyclooctaphane
AT raghunathanr 2448trioxa21aza13612tribenzena223bicyclo330octanacyclooctaphane

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