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Poly[[[diaqua­cobalt(II)]-bis­[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) N (3):N (3′)]] dichloride tetra­hydrate]

In the title compound, {[Co(C(10)H(14)N(4))(2)(H(2)O)(2)]Cl(2)·4H(2)O}(n), the Co(II) atom and the mid-point of the 1,1′-butane-1,4-diyl­diimidazole ligands lie on inversion centers. The Co(II) atom is six-coordinated in a slightly distorted octa­hedral environment by four N atoms from four differen...

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Autores principales: Su, Yu, Hou, Yan-Jun, Sun, Zhi-Zhong, Hou, Guang-Feng, Gao, Jin-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968895/
https://www.ncbi.nlm.nih.gov/pubmed/21582325
http://dx.doi.org/10.1107/S1600536809007478
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author Su, Yu
Hou, Yan-Jun
Sun, Zhi-Zhong
Hou, Guang-Feng
Gao, Jin-Sheng
author_facet Su, Yu
Hou, Yan-Jun
Sun, Zhi-Zhong
Hou, Guang-Feng
Gao, Jin-Sheng
author_sort Su, Yu
collection PubMed
description In the title compound, {[Co(C(10)H(14)N(4))(2)(H(2)O)(2)]Cl(2)·4H(2)O}(n), the Co(II) atom and the mid-point of the 1,1′-butane-1,4-diyl­diimidazole ligands lie on inversion centers. The Co(II) atom is six-coordinated in a slightly distorted octa­hedral environment by four N atoms from four different ligands and by two O atoms from the water mol­ecules. The Co(II) atoms are bridged by the ligands into a (4,4) net. Adjacent nets are linked to the chloride anions and uncoordinated water mol­ecules via O—H⋯Cl and O—H⋯O hydrogen bonds, generating a three-dimensional supra­molecular structure.
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spelling pubmed-29688952010-12-30 Poly[[[diaqua­cobalt(II)]-bis­[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) N (3):N (3′)]] dichloride tetra­hydrate] Su, Yu Hou, Yan-Jun Sun, Zhi-Zhong Hou, Guang-Feng Gao, Jin-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Co(C(10)H(14)N(4))(2)(H(2)O)(2)]Cl(2)·4H(2)O}(n), the Co(II) atom and the mid-point of the 1,1′-butane-1,4-diyl­diimidazole ligands lie on inversion centers. The Co(II) atom is six-coordinated in a slightly distorted octa­hedral environment by four N atoms from four different ligands and by two O atoms from the water mol­ecules. The Co(II) atoms are bridged by the ligands into a (4,4) net. Adjacent nets are linked to the chloride anions and uncoordinated water mol­ecules via O—H⋯Cl and O—H⋯O hydrogen bonds, generating a three-dimensional supra­molecular structure. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2968895/ /pubmed/21582325 http://dx.doi.org/10.1107/S1600536809007478 Text en © Su et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Su, Yu
Hou, Yan-Jun
Sun, Zhi-Zhong
Hou, Guang-Feng
Gao, Jin-Sheng
Poly[[[diaqua­cobalt(II)]-bis­[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) N (3):N (3′)]] dichloride tetra­hydrate]
title Poly[[[diaqua­cobalt(II)]-bis­[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) N (3):N (3′)]] dichloride tetra­hydrate]
title_full Poly[[[diaqua­cobalt(II)]-bis­[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) N (3):N (3′)]] dichloride tetra­hydrate]
title_fullStr Poly[[[diaqua­cobalt(II)]-bis­[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) N (3):N (3′)]] dichloride tetra­hydrate]
title_full_unstemmed Poly[[[diaqua­cobalt(II)]-bis­[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) N (3):N (3′)]] dichloride tetra­hydrate]
title_short Poly[[[diaqua­cobalt(II)]-bis­[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) N (3):N (3′)]] dichloride tetra­hydrate]
title_sort poly[[[diaqua­cobalt(ii)]-bis­[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) n (3):n (3′)]] dichloride tetra­hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968895/
https://www.ncbi.nlm.nih.gov/pubmed/21582325
http://dx.doi.org/10.1107/S1600536809007478
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