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Poly[[[diaquacobalt(II)]-bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole-κ(2) N (3):N (3′)]] dichloride tetrahydrate]
In the title compound, {[Co(C(10)H(14)N(4))(2)(H(2)O)(2)]Cl(2)·4H(2)O}(n), the Co(II) atom and the mid-point of the 1,1′-butane-1,4-diyldiimidazole ligands lie on inversion centers. The Co(II) atom is six-coordinated in a slightly distorted octahedral environment by four N atoms from four differen...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968895/ https://www.ncbi.nlm.nih.gov/pubmed/21582325 http://dx.doi.org/10.1107/S1600536809007478 |
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author | Su, Yu Hou, Yan-Jun Sun, Zhi-Zhong Hou, Guang-Feng Gao, Jin-Sheng |
author_facet | Su, Yu Hou, Yan-Jun Sun, Zhi-Zhong Hou, Guang-Feng Gao, Jin-Sheng |
author_sort | Su, Yu |
collection | PubMed |
description | In the title compound, {[Co(C(10)H(14)N(4))(2)(H(2)O)(2)]Cl(2)·4H(2)O}(n), the Co(II) atom and the mid-point of the 1,1′-butane-1,4-diyldiimidazole ligands lie on inversion centers. The Co(II) atom is six-coordinated in a slightly distorted octahedral environment by four N atoms from four different ligands and by two O atoms from the water molecules. The Co(II) atoms are bridged by the ligands into a (4,4) net. Adjacent nets are linked to the chloride anions and uncoordinated water molecules via O—H⋯Cl and O—H⋯O hydrogen bonds, generating a three-dimensional supramolecular structure. |
format | Text |
id | pubmed-2968895 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29688952010-12-30 Poly[[[diaquacobalt(II)]-bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole-κ(2) N (3):N (3′)]] dichloride tetrahydrate] Su, Yu Hou, Yan-Jun Sun, Zhi-Zhong Hou, Guang-Feng Gao, Jin-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Co(C(10)H(14)N(4))(2)(H(2)O)(2)]Cl(2)·4H(2)O}(n), the Co(II) atom and the mid-point of the 1,1′-butane-1,4-diyldiimidazole ligands lie on inversion centers. The Co(II) atom is six-coordinated in a slightly distorted octahedral environment by four N atoms from four different ligands and by two O atoms from the water molecules. The Co(II) atoms are bridged by the ligands into a (4,4) net. Adjacent nets are linked to the chloride anions and uncoordinated water molecules via O—H⋯Cl and O—H⋯O hydrogen bonds, generating a three-dimensional supramolecular structure. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2968895/ /pubmed/21582325 http://dx.doi.org/10.1107/S1600536809007478 Text en © Su et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Su, Yu Hou, Yan-Jun Sun, Zhi-Zhong Hou, Guang-Feng Gao, Jin-Sheng Poly[[[diaquacobalt(II)]-bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole-κ(2) N (3):N (3′)]] dichloride tetrahydrate] |
title | Poly[[[diaquacobalt(II)]-bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole-κ(2)
N
(3):N
(3′)]] dichloride tetrahydrate] |
title_full | Poly[[[diaquacobalt(II)]-bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole-κ(2)
N
(3):N
(3′)]] dichloride tetrahydrate] |
title_fullStr | Poly[[[diaquacobalt(II)]-bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole-κ(2)
N
(3):N
(3′)]] dichloride tetrahydrate] |
title_full_unstemmed | Poly[[[diaquacobalt(II)]-bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole-κ(2)
N
(3):N
(3′)]] dichloride tetrahydrate] |
title_short | Poly[[[diaquacobalt(II)]-bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole-κ(2)
N
(3):N
(3′)]] dichloride tetrahydrate] |
title_sort | poly[[[diaquacobalt(ii)]-bis[μ(2)-1,1′-(butane-1,4-diyl)diimidazole-κ(2)
n
(3):n
(3′)]] dichloride tetrahydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968895/ https://www.ncbi.nlm.nih.gov/pubmed/21582325 http://dx.doi.org/10.1107/S1600536809007478 |
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