Dichlorido{N-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine}copper(II)

The title complex, [CuCl(2)(C(9)H(13)N(3))], is mononuclear and contains a five-coordinate Cu(II) atom. The geometry of the Cu(II) atom can be described as tetra­gonal-pyramidal derived from the calculation of the value τ = 0.102. The three N atoms of the pyridine and ethane-1,2-diamine ligands and...

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Detalles Bibliográficos
Autores principales: Wang, Qiang, Bi, Cai-Feng, Wang, Da-Qi, Fan, Yu-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968900/
https://www.ncbi.nlm.nih.gov/pubmed/21582376
http://dx.doi.org/10.1107/S1600536809010149
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author Wang, Qiang
Bi, Cai-Feng
Wang, Da-Qi
Fan, Yu-Hua
author_facet Wang, Qiang
Bi, Cai-Feng
Wang, Da-Qi
Fan, Yu-Hua
author_sort Wang, Qiang
collection PubMed
description The title complex, [CuCl(2)(C(9)H(13)N(3))], is mononuclear and contains a five-coordinate Cu(II) atom. The geometry of the Cu(II) atom can be described as tetra­gonal-pyramidal derived from the calculation of the value τ = 0.102. The three N atoms of the pyridine and ethane-1,2-diamine ligands and one Cl atom belong to the basal plane and the other Cl atom represents the axial position of the pyramid. The Cu atom is displaced by 0.2599 (2) Å from the basal plane towards the axial Cl atom. In the crystal, mol­ecules are linked into chains by inter­molecular N—H⋯Cl and C—H⋯Cl hydrogen bonds.
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spelling pubmed-29689002010-12-30 Dichlorido{N-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine}copper(II) Wang, Qiang Bi, Cai-Feng Wang, Da-Qi Fan, Yu-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [CuCl(2)(C(9)H(13)N(3))], is mononuclear and contains a five-coordinate Cu(II) atom. The geometry of the Cu(II) atom can be described as tetra­gonal-pyramidal derived from the calculation of the value τ = 0.102. The three N atoms of the pyridine and ethane-1,2-diamine ligands and one Cl atom belong to the basal plane and the other Cl atom represents the axial position of the pyramid. The Cu atom is displaced by 0.2599 (2) Å from the basal plane towards the axial Cl atom. In the crystal, mol­ecules are linked into chains by inter­molecular N—H⋯Cl and C—H⋯Cl hydrogen bonds. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968900/ /pubmed/21582376 http://dx.doi.org/10.1107/S1600536809010149 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Qiang
Bi, Cai-Feng
Wang, Da-Qi
Fan, Yu-Hua
Dichlorido{N-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine}copper(II)
title Dichlorido{N-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine}copper(II)
title_full Dichlorido{N-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine}copper(II)
title_fullStr Dichlorido{N-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine}copper(II)
title_full_unstemmed Dichlorido{N-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine}copper(II)
title_short Dichlorido{N-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine}copper(II)
title_sort dichlorido{n-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968900/
https://www.ncbi.nlm.nih.gov/pubmed/21582376
http://dx.doi.org/10.1107/S1600536809010149
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