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O-4-Chlorobenzoyl diphenylselenophosphinate
The title compound, C(19)H(14)ClO(2)PSe, was obtained in the reaction of the diphenylmonoselenophosphinic acid ammonium salt with 4-chlorobenzoyl chloride. The dihedral angle between the P-bonded aromatic rings is 72.64 (14)°. Packing of the molecules in the crystal is reinforced by π–π stacking...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968906/ https://www.ncbi.nlm.nih.gov/pubmed/21582572 http://dx.doi.org/10.1107/S1600536809009313 |
| Sumario: | The title compound, C(19)H(14)ClO(2)PSe, was obtained in the reaction of the diphenylmonoselenophosphinic acid ammonium salt with 4-chlorobenzoyl chloride. The dihedral angle between the P-bonded aromatic rings is 72.64 (14)°. Packing of the molecules in the crystal is reinforced by π–π stacking interactions between two inversion-related 4-chlorobenzene rings [centroid-centroid separation = 4.189 (2) Å] and a C—H⋯O interaction also occurs. |
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