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O-4-Chlorobenzoyl diphenylselenophosphinate
The title compound, C(19)H(14)ClO(2)PSe, was obtained in the reaction of the diphenylmonoselenophosphinic acid ammonium salt with 4-chlorobenzoyl chloride. The dihedral angle between the P-bonded aromatic rings is 72.64 (14)°. Packing of the molecules in the crystal is reinforced by π–π stacking...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968906/ https://www.ncbi.nlm.nih.gov/pubmed/21582572 http://dx.doi.org/10.1107/S1600536809009313 |
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author | Cholewinski, Grzegorz Chojnacki, Jaroslaw Pikies, Jerzy Rachon, Janusz |
author_facet | Cholewinski, Grzegorz Chojnacki, Jaroslaw Pikies, Jerzy Rachon, Janusz |
author_sort | Cholewinski, Grzegorz |
collection | PubMed |
description | The title compound, C(19)H(14)ClO(2)PSe, was obtained in the reaction of the diphenylmonoselenophosphinic acid ammonium salt with 4-chlorobenzoyl chloride. The dihedral angle between the P-bonded aromatic rings is 72.64 (14)°. Packing of the molecules in the crystal is reinforced by π–π stacking interactions between two inversion-related 4-chlorobenzene rings [centroid-centroid separation = 4.189 (2) Å] and a C—H⋯O interaction also occurs. |
format | Text |
id | pubmed-2968906 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29689062010-12-30 O-4-Chlorobenzoyl diphenylselenophosphinate Cholewinski, Grzegorz Chojnacki, Jaroslaw Pikies, Jerzy Rachon, Janusz Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(14)ClO(2)PSe, was obtained in the reaction of the diphenylmonoselenophosphinic acid ammonium salt with 4-chlorobenzoyl chloride. The dihedral angle between the P-bonded aromatic rings is 72.64 (14)°. Packing of the molecules in the crystal is reinforced by π–π stacking interactions between two inversion-related 4-chlorobenzene rings [centroid-centroid separation = 4.189 (2) Å] and a C—H⋯O interaction also occurs. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968906/ /pubmed/21582572 http://dx.doi.org/10.1107/S1600536809009313 Text en © Cholewinski et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Cholewinski, Grzegorz Chojnacki, Jaroslaw Pikies, Jerzy Rachon, Janusz O-4-Chlorobenzoyl diphenylselenophosphinate |
title |
O-4-Chlorobenzoyl diphenylselenophosphinate |
title_full |
O-4-Chlorobenzoyl diphenylselenophosphinate |
title_fullStr |
O-4-Chlorobenzoyl diphenylselenophosphinate |
title_full_unstemmed |
O-4-Chlorobenzoyl diphenylselenophosphinate |
title_short |
O-4-Chlorobenzoyl diphenylselenophosphinate |
title_sort | o-4-chlorobenzoyl diphenylselenophosphinate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968906/ https://www.ncbi.nlm.nih.gov/pubmed/21582572 http://dx.doi.org/10.1107/S1600536809009313 |
work_keys_str_mv | AT cholewinskigrzegorz o4chlorobenzoyldiphenylselenophosphinate AT chojnackijaroslaw o4chlorobenzoyldiphenylselenophosphinate AT pikiesjerzy o4chlorobenzoyldiphenylselenophosphinate AT rachonjanusz o4chlorobenzoyldiphenylselenophosphinate |