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{4-Bromo-2-[(2-morpholinoeth­yl)imino­meth­yl]phenolato}iodido(methanol)zinc(II)

The title compound, [Zn(C(13)H(16)BrN(2)O(2))I(CH(3)OH)], is a new mononuclear zinc(II) complex synthesized by the reaction of equimolar quanti­ties of 5-bromo­salicylaldehyde, 2-morpholinoethyl­amine and ZnI(2) in methanol. The Zn atom is four-coordinate in a distorted tetra­hedral geometry, bindin...

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Detalles Bibliográficos
Autor principal: Han, Cheng-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968908/
https://www.ncbi.nlm.nih.gov/pubmed/21582360
http://dx.doi.org/10.1107/S1600536809009234
Descripción
Sumario:The title compound, [Zn(C(13)H(16)BrN(2)O(2))I(CH(3)OH)], is a new mononuclear zinc(II) complex synthesized by the reaction of equimolar quanti­ties of 5-bromo­salicylaldehyde, 2-morpholinoethyl­amine and ZnI(2) in methanol. The Zn atom is four-coordinate in a distorted tetra­hedral geometry, binding to a phenolate O and an imine N atom of the Schiff base ligand, the O atom of a methanol mol­ecule and one I(−) anion. In the crystal structure, adjacent mol­ecules are linked through inter­molecular O—H⋯O hydrogen bonds, forming centrosymmetric dimers.