{4-Bromo-2-[(2-morpholinoeth­yl)imino­meth­yl]phenolato}iodido(methanol)zinc(II)

The title compound, [Zn(C(13)H(16)BrN(2)O(2))I(CH(3)OH)], is a new mononuclear zinc(II) complex synthesized by the reaction of equimolar quanti­ties of 5-bromo­salicylaldehyde, 2-morpholinoethyl­amine and ZnI(2) in methanol. The Zn atom is four-coordinate in a distorted tetra­hedral geometry, bindin...

Descripción completa

Detalles Bibliográficos
Autor principal: Han, Cheng-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968908/
https://www.ncbi.nlm.nih.gov/pubmed/21582360
http://dx.doi.org/10.1107/S1600536809009234
_version_ 1782190004590608384
author Han, Cheng-Li
author_facet Han, Cheng-Li
author_sort Han, Cheng-Li
collection PubMed
description The title compound, [Zn(C(13)H(16)BrN(2)O(2))I(CH(3)OH)], is a new mononuclear zinc(II) complex synthesized by the reaction of equimolar quanti­ties of 5-bromo­salicylaldehyde, 2-morpholinoethyl­amine and ZnI(2) in methanol. The Zn atom is four-coordinate in a distorted tetra­hedral geometry, binding to a phenolate O and an imine N atom of the Schiff base ligand, the O atom of a methanol mol­ecule and one I(−) anion. In the crystal structure, adjacent mol­ecules are linked through inter­molecular O—H⋯O hydrogen bonds, forming centrosymmetric dimers.
format Text
id pubmed-2968908
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29689082010-12-30 {4-Bromo-2-[(2-morpholinoeth­yl)imino­meth­yl]phenolato}iodido(methanol)zinc(II) Han, Cheng-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(C(13)H(16)BrN(2)O(2))I(CH(3)OH)], is a new mononuclear zinc(II) complex synthesized by the reaction of equimolar quanti­ties of 5-bromo­salicylaldehyde, 2-morpholinoethyl­amine and ZnI(2) in methanol. The Zn atom is four-coordinate in a distorted tetra­hedral geometry, binding to a phenolate O and an imine N atom of the Schiff base ligand, the O atom of a methanol mol­ecule and one I(−) anion. In the crystal structure, adjacent mol­ecules are linked through inter­molecular O—H⋯O hydrogen bonds, forming centrosymmetric dimers. International Union of Crystallography 2009-03-19 /pmc/articles/PMC2968908/ /pubmed/21582360 http://dx.doi.org/10.1107/S1600536809009234 Text en © Cheng-Li Han 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Han, Cheng-Li
{4-Bromo-2-[(2-morpholinoeth­yl)imino­meth­yl]phenolato}iodido(methanol)zinc(II)
title {4-Bromo-2-[(2-morpholinoeth­yl)imino­meth­yl]phenolato}iodido(methanol)zinc(II)
title_full {4-Bromo-2-[(2-morpholinoeth­yl)imino­meth­yl]phenolato}iodido(methanol)zinc(II)
title_fullStr {4-Bromo-2-[(2-morpholinoeth­yl)imino­meth­yl]phenolato}iodido(methanol)zinc(II)
title_full_unstemmed {4-Bromo-2-[(2-morpholinoeth­yl)imino­meth­yl]phenolato}iodido(methanol)zinc(II)
title_short {4-Bromo-2-[(2-morpholinoeth­yl)imino­meth­yl]phenolato}iodido(methanol)zinc(II)
title_sort {4-bromo-2-[(2-morpholinoeth­yl)imino­meth­yl]phenolato}iodido(methanol)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968908/
https://www.ncbi.nlm.nih.gov/pubmed/21582360
http://dx.doi.org/10.1107/S1600536809009234
work_keys_str_mv AT hanchengli 4bromo22morpholinoethyliminomethylphenolatoiodidomethanolzincii

Ejemplares similares