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{μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ(4) O (6),O (1),O (1′),O (6′):2κ(4) O (1),N,N′,O (1′)}(methanol-1κO)(perchlorato-1κO)nickel(II)sodium
The molecule of the title compound, [NaNi(C(18)H(18)N(2)O(4))(ClO(4))(CH(3)OH)], is almost planar, the maximum deviation from the molecular plane being 5.3 (1) Å. The Ni(2+) ion is N(2)O(2) coordinated by the Schiff base ligand, leading to a slightly distorted square-planar environment. The Na atom...
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968922/ https://www.ncbi.nlm.nih.gov/pubmed/21582346 http://dx.doi.org/10.1107/S1600536809007776 |
| _version_ | 1782190009324929024 |
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| author | Xiao, Hui-Quan |
| author_facet | Xiao, Hui-Quan |
| author_sort | Xiao, Hui-Quan |
| collection | PubMed |
| description | The molecule of the title compound, [NaNi(C(18)H(18)N(2)O(4))(ClO(4))(CH(3)OH)], is almost planar, the maximum deviation from the molecular plane being 5.3 (1) Å. The Ni(2+) ion is N(2)O(2) coordinated by the Schiff base ligand, leading to a slightly distorted square-planar environment. The Na atom is chelated by the four O atoms of the Schiff base ligand and is coordinated by the O atoms of a methanol ligand and a perchlorate anion. The perchlorate ion is disordered over two sites with occupancies 0.723 (12):0.277 (12). |
| format | Text |
| id | pubmed-2968922 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29689222010-12-30 {μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ(4) O (6),O (1),O (1′),O (6′):2κ(4) O (1),N,N′,O (1′)}(methanol-1κO)(perchlorato-1κO)nickel(II)sodium Xiao, Hui-Quan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The molecule of the title compound, [NaNi(C(18)H(18)N(2)O(4))(ClO(4))(CH(3)OH)], is almost planar, the maximum deviation from the molecular plane being 5.3 (1) Å. The Ni(2+) ion is N(2)O(2) coordinated by the Schiff base ligand, leading to a slightly distorted square-planar environment. The Na atom is chelated by the four O atoms of the Schiff base ligand and is coordinated by the O atoms of a methanol ligand and a perchlorate anion. The perchlorate ion is disordered over two sites with occupancies 0.723 (12):0.277 (12). International Union of Crystallography 2009-03-14 /pmc/articles/PMC2968922/ /pubmed/21582346 http://dx.doi.org/10.1107/S1600536809007776 Text en © Hui-Quan Xiao 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Xiao, Hui-Quan {μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ(4) O (6),O (1),O (1′),O (6′):2κ(4) O (1),N,N′,O (1′)}(methanol-1κO)(perchlorato-1κO)nickel(II)sodium |
| title | {μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ(4)
O
(6),O
(1),O
(1′),O
(6′):2κ(4)
O
(1),N,N′,O
(1′)}(methanol-1κO)(perchlorato-1κO)nickel(II)sodium |
| title_full | {μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ(4)
O
(6),O
(1),O
(1′),O
(6′):2κ(4)
O
(1),N,N′,O
(1′)}(methanol-1κO)(perchlorato-1κO)nickel(II)sodium |
| title_fullStr | {μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ(4)
O
(6),O
(1),O
(1′),O
(6′):2κ(4)
O
(1),N,N′,O
(1′)}(methanol-1κO)(perchlorato-1κO)nickel(II)sodium |
| title_full_unstemmed | {μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ(4)
O
(6),O
(1),O
(1′),O
(6′):2κ(4)
O
(1),N,N′,O
(1′)}(methanol-1κO)(perchlorato-1κO)nickel(II)sodium |
| title_short | {μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ(4)
O
(6),O
(1),O
(1′),O
(6′):2κ(4)
O
(1),N,N′,O
(1′)}(methanol-1κO)(perchlorato-1κO)nickel(II)sodium |
| title_sort | {μ-6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ(4)
o
(6),o
(1),o
(1′),o
(6′):2κ(4)
o
(1),n,n′,o
(1′)}(methanol-1κo)(perchlorato-1κo)nickel(ii)sodium |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968922/ https://www.ncbi.nlm.nih.gov/pubmed/21582346 http://dx.doi.org/10.1107/S1600536809007776 |
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