Poly[[tri-μ-cyanido-cyanido(1,4,10,13-tetra­oxa-7,16-diaza­cyclo­octa­deca­ne)barium(II)platinum(II)] hemihydrate]

The title compound, {[BaPt(CN)(4)(C(12)H(26)N(2)O(4))]·0.5H(2)O}(n), is a two-dimensional coordination polymer in which the sheets are oriented approximately parallel to the ([Image: see text]01) set of crystal planes. In the crystal structure, disordered water mol­ecules (half occupancy) connect th...

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Detalles Bibliográficos
Autores principales: Olmstead, Marilyn M., Beavers, Christine M., Paw U, Latisha
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968926/
https://www.ncbi.nlm.nih.gov/pubmed/21582352
http://dx.doi.org/10.1107/S1600536809008915
Descripción
Sumario:The title compound, {[BaPt(CN)(4)(C(12)H(26)N(2)O(4))]·0.5H(2)O}(n), is a two-dimensional coordination polymer in which the sheets are oriented approximately parallel to the ([Image: see text]01) set of crystal planes. In the crystal structure, disordered water mol­ecules (half occupancy) connect the sheets into a three-dimensional network via inter­molecular O—H⋯O hydrogen bonds. An N—H⋯N inter­action is also present. The shortest Pt⋯Pt contacts are 7.5969 (4) Å by an inversion relationship and 7.6781 (4) Å by translation along the a axis.

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