Poly[[tri-μ-cyanido-cyanido(1,4,10,13-tetra­oxa-7,16-diaza­cyclo­octa­deca­ne)barium(II)platinum(II)] hemihydrate]

The title compound, {[BaPt(CN)(4)(C(12)H(26)N(2)O(4))]·0.5H(2)O}(n), is a two-dimensional coordination polymer in which the sheets are oriented approximately parallel to the ([Image: see text]01) set of crystal planes. In the crystal structure, disordered water mol­ecules (half occupancy) connect th...

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Detalles Bibliográficos
Autores principales: Olmstead, Marilyn M., Beavers, Christine M., Paw U, Latisha
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968926/
https://www.ncbi.nlm.nih.gov/pubmed/21582352
http://dx.doi.org/10.1107/S1600536809008915
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author Olmstead, Marilyn M.
Beavers, Christine M.
Paw U, Latisha
author_facet Olmstead, Marilyn M.
Beavers, Christine M.
Paw U, Latisha
author_sort Olmstead, Marilyn M.
collection PubMed
description The title compound, {[BaPt(CN)(4)(C(12)H(26)N(2)O(4))]·0.5H(2)O}(n), is a two-dimensional coordination polymer in which the sheets are oriented approximately parallel to the ([Image: see text]01) set of crystal planes. In the crystal structure, disordered water mol­ecules (half occupancy) connect the sheets into a three-dimensional network via inter­molecular O—H⋯O hydrogen bonds. An N—H⋯N inter­action is also present. The shortest Pt⋯Pt contacts are 7.5969 (4) Å by an inversion relationship and 7.6781 (4) Å by translation along the a axis.
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spelling pubmed-29689262010-12-30 Poly[[tri-μ-cyanido-cyanido(1,4,10,13-tetra­oxa-7,16-diaza­cyclo­octa­deca­ne)barium(II)platinum(II)] hemihydrate] Olmstead, Marilyn M. Beavers, Christine M. Paw U, Latisha Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[BaPt(CN)(4)(C(12)H(26)N(2)O(4))]·0.5H(2)O}(n), is a two-dimensional coordination polymer in which the sheets are oriented approximately parallel to the ([Image: see text]01) set of crystal planes. In the crystal structure, disordered water mol­ecules (half occupancy) connect the sheets into a three-dimensional network via inter­molecular O—H⋯O hydrogen bonds. An N—H⋯N inter­action is also present. The shortest Pt⋯Pt contacts are 7.5969 (4) Å by an inversion relationship and 7.6781 (4) Å by translation along the a axis. International Union of Crystallography 2009-03-19 /pmc/articles/PMC2968926/ /pubmed/21582352 http://dx.doi.org/10.1107/S1600536809008915 Text en © Olmstead et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Olmstead, Marilyn M.
Beavers, Christine M.
Paw U, Latisha
Poly[[tri-μ-cyanido-cyanido(1,4,10,13-tetra­oxa-7,16-diaza­cyclo­octa­deca­ne)barium(II)platinum(II)] hemihydrate]
title Poly[[tri-μ-cyanido-cyanido(1,4,10,13-tetra­oxa-7,16-diaza­cyclo­octa­deca­ne)barium(II)platinum(II)] hemihydrate]
title_full Poly[[tri-μ-cyanido-cyanido(1,4,10,13-tetra­oxa-7,16-diaza­cyclo­octa­deca­ne)barium(II)platinum(II)] hemihydrate]
title_fullStr Poly[[tri-μ-cyanido-cyanido(1,4,10,13-tetra­oxa-7,16-diaza­cyclo­octa­deca­ne)barium(II)platinum(II)] hemihydrate]
title_full_unstemmed Poly[[tri-μ-cyanido-cyanido(1,4,10,13-tetra­oxa-7,16-diaza­cyclo­octa­deca­ne)barium(II)platinum(II)] hemihydrate]
title_short Poly[[tri-μ-cyanido-cyanido(1,4,10,13-tetra­oxa-7,16-diaza­cyclo­octa­deca­ne)barium(II)platinum(II)] hemihydrate]
title_sort poly[[tri-μ-cyanido-cyanido(1,4,10,13-tetra­oxa-7,16-diaza­cyclo­octa­deca­ne)barium(ii)platinum(ii)] hemihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968926/
https://www.ncbi.nlm.nih.gov/pubmed/21582352
http://dx.doi.org/10.1107/S1600536809008915
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AT pawulatisha polytrimcyanidocyanido141013tetraoxa716diazacyclooctadecanebariumiiplatinumiihemihydrate

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