N-(2-Furo­yl)-N′-(2-pyrid­yl)thio­urea

The title compound, C(11)H(9)N(3)O(2)S, crystallizes with two independent mol­ecules in the asymmetric unit. The central thio­urea core makes dihedral angles of −3.3 (3) and 0.6 (3)° with the furan carbonyl groups in each mol­ecule, whereas the pyridine ring is inclined by 4.63 (2) and 11.28 (7)°, r...

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Detalles Bibliográficos
Autores principales: Estévez-Hernández, O., Duque, J., Pérez, H., Santos Jr, S., Mascarenhas, Y.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968930/
https://www.ncbi.nlm.nih.gov/pubmed/21582630
http://dx.doi.org/10.1107/S1600536809011301
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author Estévez-Hernández, O.
Duque, J.
Pérez, H.
Santos Jr, S.
Mascarenhas, Y.
author_facet Estévez-Hernández, O.
Duque, J.
Pérez, H.
Santos Jr, S.
Mascarenhas, Y.
author_sort Estévez-Hernández, O.
collection PubMed
description The title compound, C(11)H(9)N(3)O(2)S, crystallizes with two independent mol­ecules in the asymmetric unit. The central thio­urea core makes dihedral angles of −3.3 (3) and 0.6 (3)° with the furan carbonyl groups in each mol­ecule, whereas the pyridine ring is inclined by 4.63 (2) and 11.28 (7)°, respectively. The trans–cis geometry of the thio­urea fragment is stabilized by an intra­molecular N—H⋯N hydrogen bond between the H atom of the cis-thio­amide group and the pyridine N atom. In the crystal structure, inter­molecular bifurcated N—H⋯S and N—H⋯O hydrogen bonds form centrosymmetric tetra­mers extending along the b axis.
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spelling pubmed-29689302010-12-30 N-(2-Furo­yl)-N′-(2-pyrid­yl)thio­urea Estévez-Hernández, O. Duque, J. Pérez, H. Santos Jr, S. Mascarenhas, Y. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(11)H(9)N(3)O(2)S, crystallizes with two independent mol­ecules in the asymmetric unit. The central thio­urea core makes dihedral angles of −3.3 (3) and 0.6 (3)° with the furan carbonyl groups in each mol­ecule, whereas the pyridine ring is inclined by 4.63 (2) and 11.28 (7)°, respectively. The trans–cis geometry of the thio­urea fragment is stabilized by an intra­molecular N—H⋯N hydrogen bond between the H atom of the cis-thio­amide group and the pyridine N atom. In the crystal structure, inter­molecular bifurcated N—H⋯S and N—H⋯O hydrogen bonds form centrosymmetric tetra­mers extending along the b axis. International Union of Crystallography 2009-03-31 /pmc/articles/PMC2968930/ /pubmed/21582630 http://dx.doi.org/10.1107/S1600536809011301 Text en © Estévez-Hernández et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Estévez-Hernández, O.
Duque, J.
Pérez, H.
Santos Jr, S.
Mascarenhas, Y.
N-(2-Furo­yl)-N′-(2-pyrid­yl)thio­urea
title N-(2-Furo­yl)-N′-(2-pyrid­yl)thio­urea
title_full N-(2-Furo­yl)-N′-(2-pyrid­yl)thio­urea
title_fullStr N-(2-Furo­yl)-N′-(2-pyrid­yl)thio­urea
title_full_unstemmed N-(2-Furo­yl)-N′-(2-pyrid­yl)thio­urea
title_short N-(2-Furo­yl)-N′-(2-pyrid­yl)thio­urea
title_sort n-(2-furo­yl)-n′-(2-pyrid­yl)thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968930/
https://www.ncbi.nlm.nih.gov/pubmed/21582630
http://dx.doi.org/10.1107/S1600536809011301
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AT mascarenhasy n2furoyln2pyridylthiourea

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