3-Methyl-2-propionamido­butanoic acid

The reaction of propionyl isothio­cyanate with valine was found to give the title compound, C(8)H(15)NO(3), instead of the expected thio­urea product. The whole mol­ecule is non-planar and the carbonyl group is cis to the methyl­butanoic acid group across the C—N bond. Inter­molecular O—H⋯O and N—H⋯...

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Detalles Bibliográficos
Autores principales: Yamin, Bohari M., Othman, Eliyanti A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968931/
https://www.ncbi.nlm.nih.gov/pubmed/21582407
http://dx.doi.org/10.1107/S1600536809007119
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author Yamin, Bohari M.
Othman, Eliyanti A.
author_facet Yamin, Bohari M.
Othman, Eliyanti A.
author_sort Yamin, Bohari M.
collection PubMed
description The reaction of propionyl isothio­cyanate with valine was found to give the title compound, C(8)H(15)NO(3), instead of the expected thio­urea product. The whole mol­ecule is non-planar and the carbonyl group is cis to the methyl­butanoic acid group across the C—N bond. Inter­molecular O—H⋯O and N—H⋯O hydrogen bonds build up a two-dimensional network developing parallel to (100).
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spelling pubmed-29689312010-12-30 3-Methyl-2-propionamido­butanoic acid Yamin, Bohari M. Othman, Eliyanti A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The reaction of propionyl isothio­cyanate with valine was found to give the title compound, C(8)H(15)NO(3), instead of the expected thio­urea product. The whole mol­ecule is non-planar and the carbonyl group is cis to the methyl­butanoic acid group across the C—N bond. Inter­molecular O—H⋯O and N—H⋯O hydrogen bonds build up a two-dimensional network developing parallel to (100). International Union of Crystallography 2009-03-06 /pmc/articles/PMC2968931/ /pubmed/21582407 http://dx.doi.org/10.1107/S1600536809007119 Text en © Yamin and Othman 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yamin, Bohari M.
Othman, Eliyanti A.
3-Methyl-2-propionamido­butanoic acid
title 3-Methyl-2-propionamido­butanoic acid
title_full 3-Methyl-2-propionamido­butanoic acid
title_fullStr 3-Methyl-2-propionamido­butanoic acid
title_full_unstemmed 3-Methyl-2-propionamido­butanoic acid
title_short 3-Methyl-2-propionamido­butanoic acid
title_sort 3-methyl-2-propionamido­butanoic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968931/
https://www.ncbi.nlm.nih.gov/pubmed/21582407
http://dx.doi.org/10.1107/S1600536809007119
work_keys_str_mv AT yaminboharim 3methyl2propionamidobutanoicacid
AT othmaneliyantia 3methyl2propionamidobutanoicacid

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