Bis[μ-N′-isobutyryl-1-oxidonaphtha­lene-2-carbohydrazidato(3-)]dipyridine­tricopper(II)

The complete mol­ecule of the title complex, [Cu(3)(C(15)H(13)N(2)O(3))(2)(C(5)H(5)N)(2)], is generated by crystallographic twofold symmetry, with the central Cu atom lying on the rotation axis: it is coordinated by two N,O-bidentate ligands in a trans-CuN(2)O(2) distorted square-planar arrangement....

Descripción completa

Detalles Bibliográficos
Autores principales: Shi, Xue-Feng, Li, Dacheng, Li, Pi-Yong, Wang, Da-Qi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968934/
https://www.ncbi.nlm.nih.gov/pubmed/21582373
http://dx.doi.org/10.1107/S1600536809009003
_version_ 1782190014043521024
author Shi, Xue-Feng
Li, Dacheng
Li, Pi-Yong
Wang, Da-Qi
author_facet Shi, Xue-Feng
Li, Dacheng
Li, Pi-Yong
Wang, Da-Qi
author_sort Shi, Xue-Feng
collection PubMed
description The complete mol­ecule of the title complex, [Cu(3)(C(15)H(13)N(2)O(3))(2)(C(5)H(5)N)(2)], is generated by crystallographic twofold symmetry, with the central Cu atom lying on the rotation axis: it is coordinated by two N,O-bidentate ligands in a trans-CuN(2)O(2) distorted square-planar arrangement. The other Cu atom is coordinated by an N,O,O′-tridentate ligand and a pyridine mol­ecule in a distorted trans-CuN(2)O(2) arrangement. In the crystal structure, a C—H⋯π inter­action occurs.
format Text
id pubmed-2968934
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29689342010-12-30 Bis[μ-N′-isobutyryl-1-oxidonaphtha­lene-2-carbohydrazidato(3-)]dipyridine­tricopper(II) Shi, Xue-Feng Li, Dacheng Li, Pi-Yong Wang, Da-Qi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete mol­ecule of the title complex, [Cu(3)(C(15)H(13)N(2)O(3))(2)(C(5)H(5)N)(2)], is generated by crystallographic twofold symmetry, with the central Cu atom lying on the rotation axis: it is coordinated by two N,O-bidentate ligands in a trans-CuN(2)O(2) distorted square-planar arrangement. The other Cu atom is coordinated by an N,O,O′-tridentate ligand and a pyridine mol­ecule in a distorted trans-CuN(2)O(2) arrangement. In the crystal structure, a C—H⋯π inter­action occurs. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968934/ /pubmed/21582373 http://dx.doi.org/10.1107/S1600536809009003 Text en © Shi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shi, Xue-Feng
Li, Dacheng
Li, Pi-Yong
Wang, Da-Qi
Bis[μ-N′-isobutyryl-1-oxidonaphtha­lene-2-carbohydrazidato(3-)]dipyridine­tricopper(II)
title Bis[μ-N′-isobutyryl-1-oxidonaphtha­lene-2-carbohydrazidato(3-)]dipyridine­tricopper(II)
title_full Bis[μ-N′-isobutyryl-1-oxidonaphtha­lene-2-carbohydrazidato(3-)]dipyridine­tricopper(II)
title_fullStr Bis[μ-N′-isobutyryl-1-oxidonaphtha­lene-2-carbohydrazidato(3-)]dipyridine­tricopper(II)
title_full_unstemmed Bis[μ-N′-isobutyryl-1-oxidonaphtha­lene-2-carbohydrazidato(3-)]dipyridine­tricopper(II)
title_short Bis[μ-N′-isobutyryl-1-oxidonaphtha­lene-2-carbohydrazidato(3-)]dipyridine­tricopper(II)
title_sort bis[μ-n′-isobutyryl-1-oxidonaphtha­lene-2-carbohydrazidato(3-)]dipyridine­tricopper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968934/
https://www.ncbi.nlm.nih.gov/pubmed/21582373
http://dx.doi.org/10.1107/S1600536809009003
work_keys_str_mv AT shixuefeng bismnisobutyryl1oxidonaphthalene2carbohydrazidato3dipyridinetricopperii
AT lidacheng bismnisobutyryl1oxidonaphthalene2carbohydrazidato3dipyridinetricopperii
AT lipiyong bismnisobutyryl1oxidonaphthalene2carbohydrazidato3dipyridinetricopperii
AT wangdaqi bismnisobutyryl1oxidonaphthalene2carbohydrazidato3dipyridinetricopperii

Ejemplares similares