A chiral three-dimensional network in poly[μ-4,4′-bipyridine-di-μ-formato-cadmium(II)]

In the title compound, [Cd(HCOO)(2)(C(10)H(8)N(2))](n), the Cd(II) ion, located on a position with 2.22 site symmetry, is surrounded by two 4,4′-bipyridine ligands and four formate ligands in a distorted octahedral CdN(2)O(4) coordination. The 4,4′-bipyridine ligands bridge the metal ions, forming o...

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Detalles Bibliográficos
Autores principales: Zhao, Li, Lin, Jian-Li, Xu, Wei, Xie, Hong-Zhen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968935/
https://www.ncbi.nlm.nih.gov/pubmed/21582372
http://dx.doi.org/10.1107/S1600536809009969
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author Zhao, Li
Lin, Jian-Li
Xu, Wei
Xie, Hong-Zhen
author_facet Zhao, Li
Lin, Jian-Li
Xu, Wei
Xie, Hong-Zhen
author_sort Zhao, Li
collection PubMed
description In the title compound, [Cd(HCOO)(2)(C(10)H(8)N(2))](n), the Cd(II) ion, located on a position with 2.22 site symmetry, is surrounded by two 4,4′-bipyridine ligands and four formate ligands in a distorted octahedral CdN(2)O(4) coordination. The 4,4′-bipyridine ligands bridge the metal ions, forming one-dimensional chains along different directions, which are further connected by formate ligands into a topologically (10(10).12(4).14)(10)(3) three-dimensional network.
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spelling pubmed-29689352010-12-30 A chiral three-dimensional network in poly[μ-4,4′-bipyridine-di-μ-formato-cadmium(II)] Zhao, Li Lin, Jian-Li Xu, Wei Xie, Hong-Zhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(HCOO)(2)(C(10)H(8)N(2))](n), the Cd(II) ion, located on a position with 2.22 site symmetry, is surrounded by two 4,4′-bipyridine ligands and four formate ligands in a distorted octahedral CdN(2)O(4) coordination. The 4,4′-bipyridine ligands bridge the metal ions, forming one-dimensional chains along different directions, which are further connected by formate ligands into a topologically (10(10).12(4).14)(10)(3) three-dimensional network. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968935/ /pubmed/21582372 http://dx.doi.org/10.1107/S1600536809009969 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Li
Lin, Jian-Li
Xu, Wei
Xie, Hong-Zhen
A chiral three-dimensional network in poly[μ-4,4′-bipyridine-di-μ-formato-cadmium(II)]
title A chiral three-dimensional network in poly[μ-4,4′-bipyridine-di-μ-formato-cadmium(II)]
title_full A chiral three-dimensional network in poly[μ-4,4′-bipyridine-di-μ-formato-cadmium(II)]
title_fullStr A chiral three-dimensional network in poly[μ-4,4′-bipyridine-di-μ-formato-cadmium(II)]
title_full_unstemmed A chiral three-dimensional network in poly[μ-4,4′-bipyridine-di-μ-formato-cadmium(II)]
title_short A chiral three-dimensional network in poly[μ-4,4′-bipyridine-di-μ-formato-cadmium(II)]
title_sort chiral three-dimensional network in poly[μ-4,4′-bipyridine-di-μ-formato-cadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968935/
https://www.ncbi.nlm.nih.gov/pubmed/21582372
http://dx.doi.org/10.1107/S1600536809009969
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