Cargando…
cis-Bis[2-(1,3-benzothiazol-2-yl)-1-(4-fluorophenyl)ethenyl](pentane-2,4-dionato-κ(2) O,O′)iridium(III)
In the title compound, [Ir(C(15)H(9)FNS)(2)(C(5)H(7)O(2))], the Ir atom is hexacoordinated by three chelating ligands, with two cyclometalated 2-(1,3-benzothiazol-2-yl)-1-(4-fluorophenyl)ethenyl ligands showing N,C-bidentate coordination and an O,O′-bidenate pentane-2,4-dionate anion, thereby f...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968936/ https://www.ncbi.nlm.nih.gov/pubmed/21582377 http://dx.doi.org/10.1107/S1600536809010204 |
_version_ | 1782190014574100480 |
---|---|
author | Xiao, Guo-Yong Lei, Peng Chi, Hai-Jun Hu, Zhi-Zhi Li, Xiao |
author_facet | Xiao, Guo-Yong Lei, Peng Chi, Hai-Jun Hu, Zhi-Zhi Li, Xiao |
author_sort | Xiao, Guo-Yong |
collection | PubMed |
description | In the title compound, [Ir(C(15)H(9)FNS)(2)(C(5)H(7)O(2))], the Ir atom is hexacoordinated by three chelating ligands, with two cyclometalated 2-(1,3-benzothiazol-2-yl)-1-(4-fluorophenyl)ethenyl ligands showing N,C-bidentate coordination and an O,O′-bidenate pentane-2,4-dionate anion, thereby forming a distorted octahedral enviroment. |
format | Text |
id | pubmed-2968936 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29689362010-12-30 cis-Bis[2-(1,3-benzothiazol-2-yl)-1-(4-fluorophenyl)ethenyl](pentane-2,4-dionato-κ(2) O,O′)iridium(III) Xiao, Guo-Yong Lei, Peng Chi, Hai-Jun Hu, Zhi-Zhi Li, Xiao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ir(C(15)H(9)FNS)(2)(C(5)H(7)O(2))], the Ir atom is hexacoordinated by three chelating ligands, with two cyclometalated 2-(1,3-benzothiazol-2-yl)-1-(4-fluorophenyl)ethenyl ligands showing N,C-bidentate coordination and an O,O′-bidenate pentane-2,4-dionate anion, thereby forming a distorted octahedral enviroment. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968936/ /pubmed/21582377 http://dx.doi.org/10.1107/S1600536809010204 Text en © Xiao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xiao, Guo-Yong Lei, Peng Chi, Hai-Jun Hu, Zhi-Zhi Li, Xiao cis-Bis[2-(1,3-benzothiazol-2-yl)-1-(4-fluorophenyl)ethenyl](pentane-2,4-dionato-κ(2) O,O′)iridium(III) |
title |
cis-Bis[2-(1,3-benzothiazol-2-yl)-1-(4-fluorophenyl)ethenyl](pentane-2,4-dionato-κ(2)
O,O′)iridium(III) |
title_full |
cis-Bis[2-(1,3-benzothiazol-2-yl)-1-(4-fluorophenyl)ethenyl](pentane-2,4-dionato-κ(2)
O,O′)iridium(III) |
title_fullStr |
cis-Bis[2-(1,3-benzothiazol-2-yl)-1-(4-fluorophenyl)ethenyl](pentane-2,4-dionato-κ(2)
O,O′)iridium(III) |
title_full_unstemmed |
cis-Bis[2-(1,3-benzothiazol-2-yl)-1-(4-fluorophenyl)ethenyl](pentane-2,4-dionato-κ(2)
O,O′)iridium(III) |
title_short |
cis-Bis[2-(1,3-benzothiazol-2-yl)-1-(4-fluorophenyl)ethenyl](pentane-2,4-dionato-κ(2)
O,O′)iridium(III) |
title_sort | cis-bis[2-(1,3-benzothiazol-2-yl)-1-(4-fluorophenyl)ethenyl](pentane-2,4-dionato-κ(2)
o,o′)iridium(iii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968936/ https://www.ncbi.nlm.nih.gov/pubmed/21582377 http://dx.doi.org/10.1107/S1600536809010204 |
work_keys_str_mv | AT xiaoguoyong cisbis213benzothiazol2yl14fluorophenylethenylpentane24dionatok2ooiridiumiii AT leipeng cisbis213benzothiazol2yl14fluorophenylethenylpentane24dionatok2ooiridiumiii AT chihaijun cisbis213benzothiazol2yl14fluorophenylethenylpentane24dionatok2ooiridiumiii AT huzhizhi cisbis213benzothiazol2yl14fluorophenylethenylpentane24dionatok2ooiridiumiii AT lixiao cisbis213benzothiazol2yl14fluorophenylethenylpentane24dionatok2ooiridiumiii |