Bis(2-amino­thia­zolium) succinate succinic acid

In the title compound, 2C(3)H(5)N(2)S(+)·C(4)H(4)O(4) (2−)·C(4)H(6)O(4), the thia­zolium ring is almost planar, with the maximum deviation from planarity being 0.0056 (8) Å for the C atom carrying the amine substituent. The N atom of the 2-amino­thia­zole mol­ecule is protonated. Both the anion and...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, John, Jain, Jebas, Samuel Robinson, Balasubramanian, T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968937/
https://www.ncbi.nlm.nih.gov/pubmed/21582477
http://dx.doi.org/10.1107/S1600536809007004
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author Fun, Hoong-Kun
John, Jain
Jebas, Samuel Robinson
Balasubramanian, T.
author_facet Fun, Hoong-Kun
John, Jain
Jebas, Samuel Robinson
Balasubramanian, T.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, 2C(3)H(5)N(2)S(+)·C(4)H(4)O(4) (2−)·C(4)H(6)O(4), the thia­zolium ring is almost planar, with the maximum deviation from planarity being 0.0056 (8) Å for the C atom carrying the amine substituent. The N atom of the 2-amino­thia­zole mol­ecule is protonated. Both the anion and the acid lie across inversion centres. The crystal packing is consolidated by inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds. Mol­ecules are stacked down the b axis.
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spelling pubmed-29689372010-12-30 Bis(2-amino­thia­zolium) succinate succinic acid Fun, Hoong-Kun John, Jain Jebas, Samuel Robinson Balasubramanian, T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, 2C(3)H(5)N(2)S(+)·C(4)H(4)O(4) (2−)·C(4)H(6)O(4), the thia­zolium ring is almost planar, with the maximum deviation from planarity being 0.0056 (8) Å for the C atom carrying the amine substituent. The N atom of the 2-amino­thia­zole mol­ecule is protonated. Both the anion and the acid lie across inversion centres. The crystal packing is consolidated by inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds. Mol­ecules are stacked down the b axis. International Union of Crystallography 2009-03-14 /pmc/articles/PMC2968937/ /pubmed/21582477 http://dx.doi.org/10.1107/S1600536809007004 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
John, Jain
Jebas, Samuel Robinson
Balasubramanian, T.
Bis(2-amino­thia­zolium) succinate succinic acid
title Bis(2-amino­thia­zolium) succinate succinic acid
title_full Bis(2-amino­thia­zolium) succinate succinic acid
title_fullStr Bis(2-amino­thia­zolium) succinate succinic acid
title_full_unstemmed Bis(2-amino­thia­zolium) succinate succinic acid
title_short Bis(2-amino­thia­zolium) succinate succinic acid
title_sort bis(2-amino­thia­zolium) succinate succinic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968937/
https://www.ncbi.nlm.nih.gov/pubmed/21582477
http://dx.doi.org/10.1107/S1600536809007004
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AT johnjain bis2aminothiazoliumsuccinatesuccinicacid
AT jebassamuelrobinson bis2aminothiazoliumsuccinatesuccinicacid
AT balasubramaniant bis2aminothiazoliumsuccinatesuccinicacid

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