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Poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxylato)manganese(II)]
In the crystal structure of the title compound, [Mn(C(12)H(6)O(4))(C(10)H(8)N(2))](n), the Mn atoms are each coordinated by four O atoms of naphthalene-1,4-dicarboxylate anions and two N atoms of two symmetry-related 4,4′-bipyridine ligands within a strongly distorted octahedra. Two of the O atoms...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968939/ https://www.ncbi.nlm.nih.gov/pubmed/21582363 http://dx.doi.org/10.1107/S1600536809009301 |
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author | Boeckmann, Jan Jess, Inke Näther, Christian |
author_facet | Boeckmann, Jan Jess, Inke Näther, Christian |
author_sort | Boeckmann, Jan |
collection | PubMed |
description | In the crystal structure of the title compound, [Mn(C(12)H(6)O(4))(C(10)H(8)N(2))](n), the Mn atoms are each coordinated by four O atoms of naphthalene-1,4-dicarboxylate anions and two N atoms of two symmetry-related 4,4′-bipyridine ligands within a strongly distorted octahedra. Two of the O atoms originate from one naphthalene-1,4-dicarboxylate anion, whereas the remaining two O atoms derive from two symmetry-equivalent naphthalene-1,4-dicarboxylate anions. Two Mn atoms are connected via the anions into dimers, which are further linked by the anions and the N-donor ligands into a three-dimensional coordination network. |
format | Text |
id | pubmed-2968939 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29689392010-12-30 Poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxylato)manganese(II)] Boeckmann, Jan Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Mn(C(12)H(6)O(4))(C(10)H(8)N(2))](n), the Mn atoms are each coordinated by four O atoms of naphthalene-1,4-dicarboxylate anions and two N atoms of two symmetry-related 4,4′-bipyridine ligands within a strongly distorted octahedra. Two of the O atoms originate from one naphthalene-1,4-dicarboxylate anion, whereas the remaining two O atoms derive from two symmetry-equivalent naphthalene-1,4-dicarboxylate anions. Two Mn atoms are connected via the anions into dimers, which are further linked by the anions and the N-donor ligands into a three-dimensional coordination network. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968939/ /pubmed/21582363 http://dx.doi.org/10.1107/S1600536809009301 Text en © Boeckmann et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Boeckmann, Jan Jess, Inke Näther, Christian Poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxylato)manganese(II)] |
title | Poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxylato)manganese(II)] |
title_full | Poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxylato)manganese(II)] |
title_fullStr | Poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxylato)manganese(II)] |
title_full_unstemmed | Poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxylato)manganese(II)] |
title_short | Poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxylato)manganese(II)] |
title_sort | poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxylato)manganese(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968939/ https://www.ncbi.nlm.nih.gov/pubmed/21582363 http://dx.doi.org/10.1107/S1600536809009301 |
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