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Poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxyl­ato)manganese(II)]

In the crystal structure of the title compound, [Mn(C(12)H(6)O(4))(C(10)H(8)N(2))](n), the Mn atoms are each coordinated by four O atoms of naphthalene-1,4-dicarboxyl­ate anions and two N atoms of two symmetry-related 4,4′-bipyridine ligands within a strongly distorted octa­hedra. Two of the O atoms...

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Detalles Bibliográficos
Autores principales: Boeckmann, Jan, Jess, Inke, Näther, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968939/
https://www.ncbi.nlm.nih.gov/pubmed/21582363
http://dx.doi.org/10.1107/S1600536809009301
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author Boeckmann, Jan
Jess, Inke
Näther, Christian
author_facet Boeckmann, Jan
Jess, Inke
Näther, Christian
author_sort Boeckmann, Jan
collection PubMed
description In the crystal structure of the title compound, [Mn(C(12)H(6)O(4))(C(10)H(8)N(2))](n), the Mn atoms are each coordinated by four O atoms of naphthalene-1,4-dicarboxyl­ate anions and two N atoms of two symmetry-related 4,4′-bipyridine ligands within a strongly distorted octa­hedra. Two of the O atoms originate from one naphthalene-1,4-dicarboxyl­ate anion, whereas the remaining two O atoms derive from two symmetry-equivalent naphthalene-1,4-dicarboxyl­ate anions. Two Mn atoms are connected via the anions into dimers, which are further linked by the anions and the N-donor ligands into a three-dimensional coordination network.
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spelling pubmed-29689392010-12-30 Poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxyl­ato)manganese(II)] Boeckmann, Jan Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Mn(C(12)H(6)O(4))(C(10)H(8)N(2))](n), the Mn atoms are each coordinated by four O atoms of naphthalene-1,4-dicarboxyl­ate anions and two N atoms of two symmetry-related 4,4′-bipyridine ligands within a strongly distorted octa­hedra. Two of the O atoms originate from one naphthalene-1,4-dicarboxyl­ate anion, whereas the remaining two O atoms derive from two symmetry-equivalent naphthalene-1,4-dicarboxyl­ate anions. Two Mn atoms are connected via the anions into dimers, which are further linked by the anions and the N-donor ligands into a three-dimensional coordination network. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968939/ /pubmed/21582363 http://dx.doi.org/10.1107/S1600536809009301 Text en © Boeckmann et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Boeckmann, Jan
Jess, Inke
Näther, Christian
Poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxyl­ato)manganese(II)]
title Poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxyl­ato)manganese(II)]
title_full Poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxyl­ato)manganese(II)]
title_fullStr Poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxyl­ato)manganese(II)]
title_full_unstemmed Poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxyl­ato)manganese(II)]
title_short Poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxyl­ato)manganese(II)]
title_sort poly[(μ-4,4′-bipyridine)(μ-naphthalene-1,4-dicarboxyl­ato)manganese(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968939/
https://www.ncbi.nlm.nih.gov/pubmed/21582363
http://dx.doi.org/10.1107/S1600536809009301
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