Bis[tris­(4-fluoro­phen­yl)phosphine-κP](tropolonato-κ(2) O,O′)copper(I)

The title compound, [Cu(C(7)H(5)O(2))(C(18)H(12)F(3)P)(2)], a copper(I) tris­(4-fluoro­phen­yl)phosphine tropolonate derivative, is the first tropolonate complex with fluorinated aryl­phosphine ligands. The Cu(I) atom has a distorted tetra­hedral coordination; the most important geometrical paramete...

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Detalles Bibliográficos
Autor principal: Steyl, Gideon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968941/
https://www.ncbi.nlm.nih.gov/pubmed/21582385
http://dx.doi.org/10.1107/S1600536809010630
Descripción
Sumario:The title compound, [Cu(C(7)H(5)O(2))(C(18)H(12)F(3)P)(2)], a copper(I) tris­(4-fluoro­phen­yl)phosphine tropolonate derivative, is the first tropolonate complex with fluorinated aryl­phosphine ligands. The Cu(I) atom has a distorted tetra­hedral coordination; the most important geometrical parameters of the mol­ecule are: Cu—P = 2.2377 (10) and 2.2335 (15) Å, Cu—O = 2.084 (2) and 2.082 (2) Å, O—Cu—O = 77.72 (10)°, P—Cu—P = 128.82 (4)° and O—C—C—O = −2.1 (5)°.

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