Bis[tris­(4-fluoro­phen­yl)phosphine-κP](tropolonato-κ(2) O,O′)copper(I)

The title compound, [Cu(C(7)H(5)O(2))(C(18)H(12)F(3)P)(2)], a copper(I) tris­(4-fluoro­phen­yl)phosphine tropolonate derivative, is the first tropolonate complex with fluorinated aryl­phosphine ligands. The Cu(I) atom has a distorted tetra­hedral coordination; the most important geometrical paramete...

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Detalles Bibliográficos
Autor principal: Steyl, Gideon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968941/
https://www.ncbi.nlm.nih.gov/pubmed/21582385
http://dx.doi.org/10.1107/S1600536809010630
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author Steyl, Gideon
author_facet Steyl, Gideon
author_sort Steyl, Gideon
collection PubMed
description The title compound, [Cu(C(7)H(5)O(2))(C(18)H(12)F(3)P)(2)], a copper(I) tris­(4-fluoro­phen­yl)phosphine tropolonate derivative, is the first tropolonate complex with fluorinated aryl­phosphine ligands. The Cu(I) atom has a distorted tetra­hedral coordination; the most important geometrical parameters of the mol­ecule are: Cu—P = 2.2377 (10) and 2.2335 (15) Å, Cu—O = 2.084 (2) and 2.082 (2) Å, O—Cu—O = 77.72 (10)°, P—Cu—P = 128.82 (4)° and O—C—C—O = −2.1 (5)°.
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spelling pubmed-29689412010-12-30 Bis[tris­(4-fluoro­phen­yl)phosphine-κP](tropolonato-κ(2) O,O′)copper(I) Steyl, Gideon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(7)H(5)O(2))(C(18)H(12)F(3)P)(2)], a copper(I) tris­(4-fluoro­phen­yl)phosphine tropolonate derivative, is the first tropolonate complex with fluorinated aryl­phosphine ligands. The Cu(I) atom has a distorted tetra­hedral coordination; the most important geometrical parameters of the mol­ecule are: Cu—P = 2.2377 (10) and 2.2335 (15) Å, Cu—O = 2.084 (2) and 2.082 (2) Å, O—Cu—O = 77.72 (10)°, P—Cu—P = 128.82 (4)° and O—C—C—O = −2.1 (5)°. International Union of Crystallography 2009-03-28 /pmc/articles/PMC2968941/ /pubmed/21582385 http://dx.doi.org/10.1107/S1600536809010630 Text en © G. Steyl 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Steyl, Gideon
Bis[tris­(4-fluoro­phen­yl)phosphine-κP](tropolonato-κ(2) O,O′)copper(I)
title Bis[tris­(4-fluoro­phen­yl)phosphine-κP](tropolonato-κ(2) O,O′)copper(I)
title_full Bis[tris­(4-fluoro­phen­yl)phosphine-κP](tropolonato-κ(2) O,O′)copper(I)
title_fullStr Bis[tris­(4-fluoro­phen­yl)phosphine-κP](tropolonato-κ(2) O,O′)copper(I)
title_full_unstemmed Bis[tris­(4-fluoro­phen­yl)phosphine-κP](tropolonato-κ(2) O,O′)copper(I)
title_short Bis[tris­(4-fluoro­phen­yl)phosphine-κP](tropolonato-κ(2) O,O′)copper(I)
title_sort bis[tris­(4-fluoro­phen­yl)phosphine-κp](tropolonato-κ(2) o,o′)copper(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968941/
https://www.ncbi.nlm.nih.gov/pubmed/21582385
http://dx.doi.org/10.1107/S1600536809010630
work_keys_str_mv AT steylgideon bistris4fluorophenylphosphinekptropolonatok2oocopperi

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