Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO)cobalt(II)

In the crystal structure of the title Co(II) complex, [Co(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the metal centre is located on an inversion center and is coordinated by two 4-formyl­benzoate (FOB), two diethyl­nicotinamide (DENA) ligands and two water mol­ecules in a slightly distorted Co...

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Autores principales: Sertçelik, Mustafa, Tercan, Barış, Şahin, Ertan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968947/
https://www.ncbi.nlm.nih.gov/pubmed/21582339
http://dx.doi.org/10.1107/S1600536809008265
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author Sertçelik, Mustafa
Tercan, Barış
Şahin, Ertan
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Sertçelik, Mustafa
Tercan, Barış
Şahin, Ertan
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Sertçelik, Mustafa
collection PubMed
description In the crystal structure of the title Co(II) complex, [Co(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the metal centre is located on an inversion center and is coordinated by two 4-formyl­benzoate (FOB), two diethyl­nicotinamide (DENA) ligands and two water mol­ecules in a slightly distorted CoO(4)N(2) octa­hedral geometry. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules into infinite chains. π–π contacts between the parallel pyridine rings of neighboring DENA ligands [centroid–centroid distance = 3.652 (3) Å] further stabilize the crystal structure.
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spelling pubmed-29689472010-12-30 Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO)cobalt(II) Sertçelik, Mustafa Tercan, Barış Şahin, Ertan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title Co(II) complex, [Co(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the metal centre is located on an inversion center and is coordinated by two 4-formyl­benzoate (FOB), two diethyl­nicotinamide (DENA) ligands and two water mol­ecules in a slightly distorted CoO(4)N(2) octa­hedral geometry. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules into infinite chains. π–π contacts between the parallel pyridine rings of neighboring DENA ligands [centroid–centroid distance = 3.652 (3) Å] further stabilize the crystal structure. International Union of Crystallography 2009-03-11 /pmc/articles/PMC2968947/ /pubmed/21582339 http://dx.doi.org/10.1107/S1600536809008265 Text en © Sertçelik et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sertçelik, Mustafa
Tercan, Barış
Şahin, Ertan
Necefoğlu, Hacali
Hökelek, Tuncer
Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO)cobalt(II)
title Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO)cobalt(II)
title_full Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO)cobalt(II)
title_fullStr Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO)cobalt(II)
title_full_unstemmed Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO)cobalt(II)
title_short Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO)cobalt(II)
title_sort diaqua­bis(n,n-diethyl­nicotinamide-κn (1))bis­(4-formyl­benzoato-κo)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968947/
https://www.ncbi.nlm.nih.gov/pubmed/21582339
http://dx.doi.org/10.1107/S1600536809008265
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