catena-Poly[[bis­(4-methyl­benzene­thiol­ato)cadium(II)]-μ-1,3-di-4-pyridylpropane]

In the title compound, [Cd(C(7)H(7)S)(2)(C(13)H(14)N(2))](n), the unique Cd(II) ion, located on a twofold rotation axis, is coordinated by two S atoms and two N atoms in a slightly distorted tetra­hedral environment. Symmetry-related Cd(II) ions are linked via bridging 1,3-di-4-pyridylpropane ligand...

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Detalles Bibliográficos
Autores principales: Zhang, Yan, Zhou, Yan, Han, Lei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968951/
https://www.ncbi.nlm.nih.gov/pubmed/21582384
http://dx.doi.org/10.1107/S1600536809010447
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author Zhang, Yan
Zhou, Yan
Han, Lei
author_facet Zhang, Yan
Zhou, Yan
Han, Lei
author_sort Zhang, Yan
collection PubMed
description In the title compound, [Cd(C(7)H(7)S)(2)(C(13)H(14)N(2))](n), the unique Cd(II) ion, located on a twofold rotation axis, is coordinated by two S atoms and two N atoms in a slightly distorted tetra­hedral environment. Symmetry-related Cd(II) ions are linked via bridging 1,3-di-4-pyridylpropane ligands, forming a zig-zag chain-structure parallel to [001]. In the crystal structure, there are weak intra­chain π–π stacking inter­actions between benzene rings, with a centroid–centroid distance of 3.825 (7) Å, and pairs of chains are inter­digitated with respect to the 4-methyl­benzene­thiol­ate groups.
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spelling pubmed-29689512010-12-30 catena-Poly[[bis­(4-methyl­benzene­thiol­ato)cadium(II)]-μ-1,3-di-4-pyridylpropane] Zhang, Yan Zhou, Yan Han, Lei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(7)H(7)S)(2)(C(13)H(14)N(2))](n), the unique Cd(II) ion, located on a twofold rotation axis, is coordinated by two S atoms and two N atoms in a slightly distorted tetra­hedral environment. Symmetry-related Cd(II) ions are linked via bridging 1,3-di-4-pyridylpropane ligands, forming a zig-zag chain-structure parallel to [001]. In the crystal structure, there are weak intra­chain π–π stacking inter­actions between benzene rings, with a centroid–centroid distance of 3.825 (7) Å, and pairs of chains are inter­digitated with respect to the 4-methyl­benzene­thiol­ate groups. International Union of Crystallography 2009-03-28 /pmc/articles/PMC2968951/ /pubmed/21582384 http://dx.doi.org/10.1107/S1600536809010447 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Yan
Zhou, Yan
Han, Lei
catena-Poly[[bis­(4-methyl­benzene­thiol­ato)cadium(II)]-μ-1,3-di-4-pyridylpropane]
title catena-Poly[[bis­(4-methyl­benzene­thiol­ato)cadium(II)]-μ-1,3-di-4-pyridylpropane]
title_full catena-Poly[[bis­(4-methyl­benzene­thiol­ato)cadium(II)]-μ-1,3-di-4-pyridylpropane]
title_fullStr catena-Poly[[bis­(4-methyl­benzene­thiol­ato)cadium(II)]-μ-1,3-di-4-pyridylpropane]
title_full_unstemmed catena-Poly[[bis­(4-methyl­benzene­thiol­ato)cadium(II)]-μ-1,3-di-4-pyridylpropane]
title_short catena-Poly[[bis­(4-methyl­benzene­thiol­ato)cadium(II)]-μ-1,3-di-4-pyridylpropane]
title_sort catena-poly[[bis­(4-methyl­benzene­thiol­ato)cadium(ii)]-μ-1,3-di-4-pyridylpropane]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968951/
https://www.ncbi.nlm.nih.gov/pubmed/21582384
http://dx.doi.org/10.1107/S1600536809010447
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