Poly[bis­(μ(3)-5-nitro­isophthalato)bis­(1,10-phenanthroline)dimanganese(II)]

The title complex, [Mn(2)(C(8)H(3)NO(6))(2)(C(12)H(8)N(2))(2)](n), was synthesized under hydro­thermal conditions. The structure contains two independent Mn(II) atoms, each coordinated in a distorted octa­hedral MnN(2)O(4) geometry. [Mn(2)(phen)(2)] units (phen = 1,10-phenantroline) are bridged by 5...

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Detalles Bibliográficos
Autores principales: Wang, Hai-Dong, Li, Min-Min, He, Hong-Yin, Jiang, Fu-Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968954/
https://www.ncbi.nlm.nih.gov/pubmed/21582358
http://dx.doi.org/10.1107/S1600536809009052
Descripción
Sumario:The title complex, [Mn(2)(C(8)H(3)NO(6))(2)(C(12)H(8)N(2))(2)](n), was synthesized under hydro­thermal conditions. The structure contains two independent Mn(II) atoms, each coordinated in a distorted octa­hedral MnN(2)O(4) geometry. [Mn(2)(phen)(2)] units (phen = 1,10-phenantroline) are bridged by 5-nitro­isophthalate (nip) ligands into ladder-like chains parallel to [100]. Adjacent polymeric chains are linked by C—H⋯O and π–π inter­actions [centroid-to-centroid distance = 3.6369 (12) Å] into a two-dimensional framework parallel to (010).

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