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Poly[bis(μ(3)-5-nitroisophthalato)bis(1,10-phenanthroline)dimanganese(II)]
The title complex, [Mn(2)(C(8)H(3)NO(6))(2)(C(12)H(8)N(2))(2)](n), was synthesized under hydrothermal conditions. The structure contains two independent Mn(II) atoms, each coordinated in a distorted octahedral MnN(2)O(4) geometry. [Mn(2)(phen)(2)] units (phen = 1,10-phenantroline) are bridged by 5...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968954/ https://www.ncbi.nlm.nih.gov/pubmed/21582358 http://dx.doi.org/10.1107/S1600536809009052 |
| _version_ | 1782190020395794432 |
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| author | Wang, Hai-Dong Li, Min-Min He, Hong-Yin Jiang, Fu-Bin |
| author_facet | Wang, Hai-Dong Li, Min-Min He, Hong-Yin Jiang, Fu-Bin |
| author_sort | Wang, Hai-Dong |
| collection | PubMed |
| description | The title complex, [Mn(2)(C(8)H(3)NO(6))(2)(C(12)H(8)N(2))(2)](n), was synthesized under hydrothermal conditions. The structure contains two independent Mn(II) atoms, each coordinated in a distorted octahedral MnN(2)O(4) geometry. [Mn(2)(phen)(2)] units (phen = 1,10-phenantroline) are bridged by 5-nitroisophthalate (nip) ligands into ladder-like chains parallel to [100]. Adjacent polymeric chains are linked by C—H⋯O and π–π interactions [centroid-to-centroid distance = 3.6369 (12) Å] into a two-dimensional framework parallel to (010). |
| format | Text |
| id | pubmed-2968954 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29689542010-12-30 Poly[bis(μ(3)-5-nitroisophthalato)bis(1,10-phenanthroline)dimanganese(II)] Wang, Hai-Dong Li, Min-Min He, Hong-Yin Jiang, Fu-Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Mn(2)(C(8)H(3)NO(6))(2)(C(12)H(8)N(2))(2)](n), was synthesized under hydrothermal conditions. The structure contains two independent Mn(II) atoms, each coordinated in a distorted octahedral MnN(2)O(4) geometry. [Mn(2)(phen)(2)] units (phen = 1,10-phenantroline) are bridged by 5-nitroisophthalate (nip) ligands into ladder-like chains parallel to [100]. Adjacent polymeric chains are linked by C—H⋯O and π–π interactions [centroid-to-centroid distance = 3.6369 (12) Å] into a two-dimensional framework parallel to (010). International Union of Crystallography 2009-03-19 /pmc/articles/PMC2968954/ /pubmed/21582358 http://dx.doi.org/10.1107/S1600536809009052 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Hai-Dong Li, Min-Min He, Hong-Yin Jiang, Fu-Bin Poly[bis(μ(3)-5-nitroisophthalato)bis(1,10-phenanthroline)dimanganese(II)] |
| title | Poly[bis(μ(3)-5-nitroisophthalato)bis(1,10-phenanthroline)dimanganese(II)] |
| title_full | Poly[bis(μ(3)-5-nitroisophthalato)bis(1,10-phenanthroline)dimanganese(II)] |
| title_fullStr | Poly[bis(μ(3)-5-nitroisophthalato)bis(1,10-phenanthroline)dimanganese(II)] |
| title_full_unstemmed | Poly[bis(μ(3)-5-nitroisophthalato)bis(1,10-phenanthroline)dimanganese(II)] |
| title_short | Poly[bis(μ(3)-5-nitroisophthalato)bis(1,10-phenanthroline)dimanganese(II)] |
| title_sort | poly[bis(μ(3)-5-nitroisophthalato)bis(1,10-phenanthroline)dimanganese(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968954/ https://www.ncbi.nlm.nih.gov/pubmed/21582358 http://dx.doi.org/10.1107/S1600536809009052 |
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