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Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilodimethylidyne)]diphenolato-κ(2) O (1),N,N′,O (1′)}cobalt(III) monohydrate
The title compound, [Co(C(18)H(18)N(2)O(4))Cl(H(2)O)]·H(2)O, contains a distorted octahedral cobalt(III) complex with a 6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilodimethylidyne)]diphenolate ligand, a chloride and an aqua ligand, and also a disordered water solvent molecule (half-occupancy)....
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968959/ https://www.ncbi.nlm.nih.gov/pubmed/21582398 http://dx.doi.org/10.1107/S1600536809011167 |
| _version_ | 1782190021863800832 |
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| author | Xing, Jianxin |
| author_facet | Xing, Jianxin |
| author_sort | Xing, Jianxin |
| collection | PubMed |
| description | The title compound, [Co(C(18)H(18)N(2)O(4))Cl(H(2)O)]·H(2)O, contains a distorted octahedral cobalt(III) complex with a 6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilodimethylidyne)]diphenolate ligand, a chloride and an aqua ligand, and also a disordered water solvent molecule (half-occupancy). The Co(III) ion is coordinated in an N(2)O(3)Cl manner. Weak O—H⋯O hydrogen bonds may help to stabilize the crystal packing. |
| format | Text |
| id | pubmed-2968959 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29689592010-12-30 Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilodimethylidyne)]diphenolato-κ(2) O (1),N,N′,O (1′)}cobalt(III) monohydrate Xing, Jianxin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(18)H(18)N(2)O(4))Cl(H(2)O)]·H(2)O, contains a distorted octahedral cobalt(III) complex with a 6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilodimethylidyne)]diphenolate ligand, a chloride and an aqua ligand, and also a disordered water solvent molecule (half-occupancy). The Co(III) ion is coordinated in an N(2)O(3)Cl manner. Weak O—H⋯O hydrogen bonds may help to stabilize the crystal packing. International Union of Crystallography 2009-03-31 /pmc/articles/PMC2968959/ /pubmed/21582398 http://dx.doi.org/10.1107/S1600536809011167 Text en © Jianxin Xing 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Xing, Jianxin Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilodimethylidyne)]diphenolato-κ(2) O (1),N,N′,O (1′)}cobalt(III) monohydrate |
| title | Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilodimethylidyne)]diphenolato-κ(2)
O
(1),N,N′,O
(1′)}cobalt(III) monohydrate |
| title_full | Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilodimethylidyne)]diphenolato-κ(2)
O
(1),N,N′,O
(1′)}cobalt(III) monohydrate |
| title_fullStr | Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilodimethylidyne)]diphenolato-κ(2)
O
(1),N,N′,O
(1′)}cobalt(III) monohydrate |
| title_full_unstemmed | Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilodimethylidyne)]diphenolato-κ(2)
O
(1),N,N′,O
(1′)}cobalt(III) monohydrate |
| title_short | Aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilodimethylidyne)]diphenolato-κ(2)
O
(1),N,N′,O
(1′)}cobalt(III) monohydrate |
| title_sort | aquachlorido{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilodimethylidyne)]diphenolato-κ(2)
o
(1),n,n′,o
(1′)}cobalt(iii) monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968959/ https://www.ncbi.nlm.nih.gov/pubmed/21582398 http://dx.doi.org/10.1107/S1600536809011167 |
| work_keys_str_mv | AT xingjianxin aquachlorido66dimethoxy22ethane12diylbisnitrilodimethylidynediphenolatok2o1nno1cobaltiiimonohydrate |