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(S,R,Rp)-N,N-Dimethyl-1-{2-[(1-phenyl­ethyl)amino­meth­yl]ferrocen­yl}ethanamine

The title chiral ferrocene compound, [Fe(C(5)H(5))(C(18)H(25)N(2))], contains one planar and two central chiral centers. It is of inter­est with respect to asymmetric catalysis. The absolute configuration of the planar chirality is Rp at the ferrocene group and those of the two C chiral centers are...

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Detalles Bibliográficos
Autores principales: Zheng, Xiu-Li, Liu, Jin-Ting
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968963/
https://www.ncbi.nlm.nih.gov/pubmed/21582371
http://dx.doi.org/10.1107/S1600536809008861
Descripción
Sumario:The title chiral ferrocene compound, [Fe(C(5)H(5))(C(18)H(25)N(2))], contains one planar and two central chiral centers. It is of inter­est with respect to asymmetric catalysis. The absolute configuration of the planar chirality is Rp at the ferrocene group and those of the two C chiral centers are R at the CH carbon of the ethanamine unit and S at the CH carbon of the phenyl­ethyl­amino substituent. In the ferrocenyl unit, the cyclo­penta­dienyl (Cp) rings are planar, with maximum deviations of 0.002 (2) Å for the substituted and 0.008 (3) Å for the unsubstituted Cp ring. The dihedral angle between the ring planes is 2.12 (15)° and the rings are twisted slightly from an eclipsed conformation by 7.06–7.60°.