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(S,R,Rp)-N,N-Dimethyl-1-{2-[(1-phenyl­ethyl)amino­meth­yl]ferrocen­yl}ethanamine

The title chiral ferrocene compound, [Fe(C(5)H(5))(C(18)H(25)N(2))], contains one planar and two central chiral centers. It is of inter­est with respect to asymmetric catalysis. The absolute configuration of the planar chirality is Rp at the ferrocene group and those of the two C chiral centers are...

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Autores principales: Zheng, Xiu-Li, Liu, Jin-Ting
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968963/
https://www.ncbi.nlm.nih.gov/pubmed/21582371
http://dx.doi.org/10.1107/S1600536809008861
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author Zheng, Xiu-Li
Liu, Jin-Ting
author_facet Zheng, Xiu-Li
Liu, Jin-Ting
author_sort Zheng, Xiu-Li
collection PubMed
description The title chiral ferrocene compound, [Fe(C(5)H(5))(C(18)H(25)N(2))], contains one planar and two central chiral centers. It is of inter­est with respect to asymmetric catalysis. The absolute configuration of the planar chirality is Rp at the ferrocene group and those of the two C chiral centers are R at the CH carbon of the ethanamine unit and S at the CH carbon of the phenyl­ethyl­amino substituent. In the ferrocenyl unit, the cyclo­penta­dienyl (Cp) rings are planar, with maximum deviations of 0.002 (2) Å for the substituted and 0.008 (3) Å for the unsubstituted Cp ring. The dihedral angle between the ring planes is 2.12 (15)° and the rings are twisted slightly from an eclipsed conformation by 7.06–7.60°.
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spelling pubmed-29689632010-12-30 (S,R,Rp)-N,N-Dimethyl-1-{2-[(1-phenyl­ethyl)amino­meth­yl]ferrocen­yl}ethanamine Zheng, Xiu-Li Liu, Jin-Ting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title chiral ferrocene compound, [Fe(C(5)H(5))(C(18)H(25)N(2))], contains one planar and two central chiral centers. It is of inter­est with respect to asymmetric catalysis. The absolute configuration of the planar chirality is Rp at the ferrocene group and those of the two C chiral centers are R at the CH carbon of the ethanamine unit and S at the CH carbon of the phenyl­ethyl­amino substituent. In the ferrocenyl unit, the cyclo­penta­dienyl (Cp) rings are planar, with maximum deviations of 0.002 (2) Å for the substituted and 0.008 (3) Å for the unsubstituted Cp ring. The dihedral angle between the ring planes is 2.12 (15)° and the rings are twisted slightly from an eclipsed conformation by 7.06–7.60°. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968963/ /pubmed/21582371 http://dx.doi.org/10.1107/S1600536809008861 Text en © Zheng and Liu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zheng, Xiu-Li
Liu, Jin-Ting
(S,R,Rp)-N,N-Dimethyl-1-{2-[(1-phenyl­ethyl)amino­meth­yl]ferrocen­yl}ethanamine
title (S,R,Rp)-N,N-Dimethyl-1-{2-[(1-phenyl­ethyl)amino­meth­yl]ferrocen­yl}ethanamine
title_full (S,R,Rp)-N,N-Dimethyl-1-{2-[(1-phenyl­ethyl)amino­meth­yl]ferrocen­yl}ethanamine
title_fullStr (S,R,Rp)-N,N-Dimethyl-1-{2-[(1-phenyl­ethyl)amino­meth­yl]ferrocen­yl}ethanamine
title_full_unstemmed (S,R,Rp)-N,N-Dimethyl-1-{2-[(1-phenyl­ethyl)amino­meth­yl]ferrocen­yl}ethanamine
title_short (S,R,Rp)-N,N-Dimethyl-1-{2-[(1-phenyl­ethyl)amino­meth­yl]ferrocen­yl}ethanamine
title_sort (s,r,rp)-n,n-dimethyl-1-{2-[(1-phenyl­ethyl)amino­meth­yl]ferrocen­yl}ethanamine
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968963/
https://www.ncbi.nlm.nih.gov/pubmed/21582371
http://dx.doi.org/10.1107/S1600536809008861
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