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Bis[diamino­(ethoxy­carbonyl­amino)­methyl­ium] sulfate

In the mol­ecule of the title compound, 2C(4)H(10)N(3)O(2) (+)·SO(4) (−), the cations are planar (r.m.s. deviations = 0.0144 and 0.0236 Å) and oriented at a dihedral angle of 62.30 (4)°. Intra­molecular N—H⋯O hydrogen bonds result in the formation of two planar six-membered rings. The cations are li...

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Autores principales: Tahir, M. Nawaz, Muir, Christy, Danish, Muhammad, Tariq, Muhammad Ilyas, Ülkü, Dinçer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968979/
https://www.ncbi.nlm.nih.gov/pubmed/21582510
http://dx.doi.org/10.1107/S160053680900912X
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author Tahir, M. Nawaz
Muir, Christy
Danish, Muhammad
Tariq, Muhammad Ilyas
Ülkü, Dinçer
author_facet Tahir, M. Nawaz
Muir, Christy
Danish, Muhammad
Tariq, Muhammad Ilyas
Ülkü, Dinçer
author_sort Tahir, M. Nawaz
collection PubMed
description In the mol­ecule of the title compound, 2C(4)H(10)N(3)O(2) (+)·SO(4) (−), the cations are planar (r.m.s. deviations = 0.0144 and 0.0236 Å) and oriented at a dihedral angle of 62.30 (4)°. Intra­molecular N—H⋯O hydrogen bonds result in the formation of two planar six-membered rings. The cations are linked to the sulfate ion through inter­molecular C—H⋯O and N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. In the crystal structure, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network.
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spelling pubmed-29689792010-12-30 Bis[diamino­(ethoxy­carbonyl­amino)­methyl­ium] sulfate Tahir, M. Nawaz Muir, Christy Danish, Muhammad Tariq, Muhammad Ilyas Ülkü, Dinçer Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, 2C(4)H(10)N(3)O(2) (+)·SO(4) (−), the cations are planar (r.m.s. deviations = 0.0144 and 0.0236 Å) and oriented at a dihedral angle of 62.30 (4)°. Intra­molecular N—H⋯O hydrogen bonds result in the formation of two planar six-membered rings. The cations are linked to the sulfate ion through inter­molecular C—H⋯O and N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. In the crystal structure, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. International Union of Crystallography 2009-03-19 /pmc/articles/PMC2968979/ /pubmed/21582510 http://dx.doi.org/10.1107/S160053680900912X Text en © Tahir et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tahir, M. Nawaz
Muir, Christy
Danish, Muhammad
Tariq, Muhammad Ilyas
Ülkü, Dinçer
Bis[diamino­(ethoxy­carbonyl­amino)­methyl­ium] sulfate
title Bis[diamino­(ethoxy­carbonyl­amino)­methyl­ium] sulfate
title_full Bis[diamino­(ethoxy­carbonyl­amino)­methyl­ium] sulfate
title_fullStr Bis[diamino­(ethoxy­carbonyl­amino)­methyl­ium] sulfate
title_full_unstemmed Bis[diamino­(ethoxy­carbonyl­amino)­methyl­ium] sulfate
title_short Bis[diamino­(ethoxy­carbonyl­amino)­methyl­ium] sulfate
title_sort bis[diamino­(ethoxy­carbonyl­amino)­methyl­ium] sulfate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968979/
https://www.ncbi.nlm.nih.gov/pubmed/21582510
http://dx.doi.org/10.1107/S160053680900912X
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