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Methyl 2-[2-((Z)-{1-trans-[2-(4-fluoro-3-methylphenyl)-2-methylcyclopropyl]ethylidene}aminooxymethyl)phenyl]-2-[(E)-methoxyimino]acetate
The title compound, C(24)H(27)FN(2)O(4), is an important intermediate in the synthesis of fungicidal strobilurin-type compounds. In the crystal structure, the oxime bond attached to the cyclopropane ring adopts a Z configuration, while the oxime bond attached to the benzene ring adopts an E config...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968980/ https://www.ncbi.nlm.nih.gov/pubmed/21582520 http://dx.doi.org/10.1107/S1600536809009064 |
Sumario: | The title compound, C(24)H(27)FN(2)O(4), is an important intermediate in the synthesis of fungicidal strobilurin-type compounds. In the crystal structure, the oxime bond attached to the cyclopropane ring adopts a Z configuration, while the oxime bond attached to the benzene ring adopts an E configuration. The fluoromethylphenyl group adopts a trans configuration with respect to the remainder of the molecule, and its mean plane forms a dihedral angle of 56.1 (1)° with the plane of the cyclopropane ring. |
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