Methyl 2-[2-((Z)-{1-trans-[2-(4-fluoro-3-methyl­phen­yl)-2-methyl­cyclo­prop­yl]ethyl­idene}amino­oxymeth­yl)phen­yl]-2-[(E)-methoxy­imino]­acetate

The title compound, C(24)H(27)FN(2)O(4), is an important inter­mediate in the synthesis of fungicidal strobilurin-type compounds. In the crystal structure, the oxime bond attached to the cyclo­propane ring adopts a Z configuration, while the oxime bond attached to the benzene ring adopts an E config...

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Detalles Bibliográficos
Autores principales: Song, Chunfeng, Ross, Ronald, Shaber, Steven, Li, Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968980/
https://www.ncbi.nlm.nih.gov/pubmed/21582520
http://dx.doi.org/10.1107/S1600536809009064
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author Song, Chunfeng
Ross, Ronald
Shaber, Steven
Li, Bin
author_facet Song, Chunfeng
Ross, Ronald
Shaber, Steven
Li, Bin
author_sort Song, Chunfeng
collection PubMed
description The title compound, C(24)H(27)FN(2)O(4), is an important inter­mediate in the synthesis of fungicidal strobilurin-type compounds. In the crystal structure, the oxime bond attached to the cyclo­propane ring adopts a Z configuration, while the oxime bond attached to the benzene ring adopts an E configuration. The fluoro­methyl­phenyl group adopts a trans configuration with respect to the remainder of the mol­ecule, and its mean plane forms a dihedral angle of 56.1 (1)° with the plane of the cyclo­propane ring.
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spelling pubmed-29689802010-12-30 Methyl 2-[2-((Z)-{1-trans-[2-(4-fluoro-3-methyl­phen­yl)-2-methyl­cyclo­prop­yl]ethyl­idene}amino­oxymeth­yl)phen­yl]-2-[(E)-methoxy­imino]­acetate Song, Chunfeng Ross, Ronald Shaber, Steven Li, Bin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(24)H(27)FN(2)O(4), is an important inter­mediate in the synthesis of fungicidal strobilurin-type compounds. In the crystal structure, the oxime bond attached to the cyclo­propane ring adopts a Z configuration, while the oxime bond attached to the benzene ring adopts an E configuration. The fluoro­methyl­phenyl group adopts a trans configuration with respect to the remainder of the mol­ecule, and its mean plane forms a dihedral angle of 56.1 (1)° with the plane of the cyclo­propane ring. International Union of Crystallography 2009-03-19 /pmc/articles/PMC2968980/ /pubmed/21582520 http://dx.doi.org/10.1107/S1600536809009064 Text en © Song et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Song, Chunfeng
Ross, Ronald
Shaber, Steven
Li, Bin
Methyl 2-[2-((Z)-{1-trans-[2-(4-fluoro-3-methyl­phen­yl)-2-methyl­cyclo­prop­yl]ethyl­idene}amino­oxymeth­yl)phen­yl]-2-[(E)-methoxy­imino]­acetate
title Methyl 2-[2-((Z)-{1-trans-[2-(4-fluoro-3-methyl­phen­yl)-2-methyl­cyclo­prop­yl]ethyl­idene}amino­oxymeth­yl)phen­yl]-2-[(E)-methoxy­imino]­acetate
title_full Methyl 2-[2-((Z)-{1-trans-[2-(4-fluoro-3-methyl­phen­yl)-2-methyl­cyclo­prop­yl]ethyl­idene}amino­oxymeth­yl)phen­yl]-2-[(E)-methoxy­imino]­acetate
title_fullStr Methyl 2-[2-((Z)-{1-trans-[2-(4-fluoro-3-methyl­phen­yl)-2-methyl­cyclo­prop­yl]ethyl­idene}amino­oxymeth­yl)phen­yl]-2-[(E)-methoxy­imino]­acetate
title_full_unstemmed Methyl 2-[2-((Z)-{1-trans-[2-(4-fluoro-3-methyl­phen­yl)-2-methyl­cyclo­prop­yl]ethyl­idene}amino­oxymeth­yl)phen­yl]-2-[(E)-methoxy­imino]­acetate
title_short Methyl 2-[2-((Z)-{1-trans-[2-(4-fluoro-3-methyl­phen­yl)-2-methyl­cyclo­prop­yl]ethyl­idene}amino­oxymeth­yl)phen­yl]-2-[(E)-methoxy­imino]­acetate
title_sort methyl 2-[2-((z)-{1-trans-[2-(4-fluoro-3-methyl­phen­yl)-2-methyl­cyclo­prop­yl]ethyl­idene}amino­oxymeth­yl)phen­yl]-2-[(e)-methoxy­imino]­acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968980/
https://www.ncbi.nlm.nih.gov/pubmed/21582520
http://dx.doi.org/10.1107/S1600536809009064
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AT rossronald methyl22z1trans24fluoro3methylphenyl2methylcyclopropylethylideneaminooxymethylphenyl2emethoxyiminoacetate
AT shabersteven methyl22z1trans24fluoro3methylphenyl2methylcyclopropylethylideneaminooxymethylphenyl2emethoxyiminoacetate
AT libin methyl22z1trans24fluoro3methylphenyl2methylcyclopropylethylideneaminooxymethylphenyl2emethoxyiminoacetate

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