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4-(Dimethyl­amino)phenyl ethynyl telluride

The title compound, C(10)H(11)NTe, is the first organyl ethynyl telluride, R—Te—C C—H, to be structurally characterized. In the L-shaped mol­ecule, the aryl moiety, viz. Me(2)NC(6)H(4)Te, is almost perpendicular to the Te—C C—H fragment. The Te—Csp (2) bond [2.115 (3) Å] is significantly longer than...

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Autores principales: Farran, Joan, Alvarez-Larena, Angel, Piniella, Joan F., Capparelli, Mario V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968982/
https://www.ncbi.nlm.nih.gov/pubmed/21582534
http://dx.doi.org/10.1107/S1600536809009404
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author Farran, Joan
Alvarez-Larena, Angel
Piniella, Joan F.
Capparelli, Mario V.
author_facet Farran, Joan
Alvarez-Larena, Angel
Piniella, Joan F.
Capparelli, Mario V.
author_sort Farran, Joan
collection PubMed
description The title compound, C(10)H(11)NTe, is the first organyl ethynyl telluride, R—Te—C C—H, to be structurally characterized. In the L-shaped mol­ecule, the aryl moiety, viz. Me(2)NC(6)H(4)Te, is almost perpendicular to the Te—C C—H fragment. The Te—Csp (2) bond [2.115 (3) Å] is significantly longer than the Te—Csp bond [2.041 (4) Å]. The Te—C C group is approximately linear [Te—C—C = 178.5 (4)° and C C = 1.161 (5) Å], while the coordination at the Te atom is angular [C—Te—C = 95.92 (14)°]. In the crystal structure, there are Csp—H⋯N hydrogen bonds which are perpendicular to the CNMe(2) group; the N atom displays some degree of pyramidalization. Centrosymmetrically related pairs of mol­ecules are linked by Te⋯π(ar­yl) inter­actions, with Te⋯Cg = 3.683 (4) Å and Csp—Te⋯Cg = 159.1 (2)° (Cg is the centroid of the benzene ring). These inter­actions lead to the formation of zigzag ribbons which run along c and are approximately parallel to (110).
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spelling pubmed-29689822010-12-30 4-(Dimethyl­amino)phenyl ethynyl telluride Farran, Joan Alvarez-Larena, Angel Piniella, Joan F. Capparelli, Mario V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(11)NTe, is the first organyl ethynyl telluride, R—Te—C C—H, to be structurally characterized. In the L-shaped mol­ecule, the aryl moiety, viz. Me(2)NC(6)H(4)Te, is almost perpendicular to the Te—C C—H fragment. The Te—Csp (2) bond [2.115 (3) Å] is significantly longer than the Te—Csp bond [2.041 (4) Å]. The Te—C C group is approximately linear [Te—C—C = 178.5 (4)° and C C = 1.161 (5) Å], while the coordination at the Te atom is angular [C—Te—C = 95.92 (14)°]. In the crystal structure, there are Csp—H⋯N hydrogen bonds which are perpendicular to the CNMe(2) group; the N atom displays some degree of pyramidalization. Centrosymmetrically related pairs of mol­ecules are linked by Te⋯π(ar­yl) inter­actions, with Te⋯Cg = 3.683 (4) Å and Csp—Te⋯Cg = 159.1 (2)° (Cg is the centroid of the benzene ring). These inter­actions lead to the formation of zigzag ribbons which run along c and are approximately parallel to (110). International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968982/ /pubmed/21582534 http://dx.doi.org/10.1107/S1600536809009404 Text en © Farran et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Farran, Joan
Alvarez-Larena, Angel
Piniella, Joan F.
Capparelli, Mario V.
4-(Dimethyl­amino)phenyl ethynyl telluride
title 4-(Dimethyl­amino)phenyl ethynyl telluride
title_full 4-(Dimethyl­amino)phenyl ethynyl telluride
title_fullStr 4-(Dimethyl­amino)phenyl ethynyl telluride
title_full_unstemmed 4-(Dimethyl­amino)phenyl ethynyl telluride
title_short 4-(Dimethyl­amino)phenyl ethynyl telluride
title_sort 4-(dimethyl­amino)phenyl ethynyl telluride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968982/
https://www.ncbi.nlm.nih.gov/pubmed/21582534
http://dx.doi.org/10.1107/S1600536809009404
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