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4-(Dimethylamino)phenyl ethynyl telluride
The title compound, C(10)H(11)NTe, is the first organyl ethynyl telluride, R—Te—C C—H, to be structurally characterized. In the L-shaped molecule, the aryl moiety, viz. Me(2)NC(6)H(4)Te, is almost perpendicular to the Te—C C—H fragment. The Te—Csp (2) bond [2.115 (3) Å] is significantly longer than...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968982/ https://www.ncbi.nlm.nih.gov/pubmed/21582534 http://dx.doi.org/10.1107/S1600536809009404 |
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author | Farran, Joan Alvarez-Larena, Angel Piniella, Joan F. Capparelli, Mario V. |
author_facet | Farran, Joan Alvarez-Larena, Angel Piniella, Joan F. Capparelli, Mario V. |
author_sort | Farran, Joan |
collection | PubMed |
description | The title compound, C(10)H(11)NTe, is the first organyl ethynyl telluride, R—Te—C C—H, to be structurally characterized. In the L-shaped molecule, the aryl moiety, viz. Me(2)NC(6)H(4)Te, is almost perpendicular to the Te—C C—H fragment. The Te—Csp (2) bond [2.115 (3) Å] is significantly longer than the Te—Csp bond [2.041 (4) Å]. The Te—C C group is approximately linear [Te—C—C = 178.5 (4)° and C C = 1.161 (5) Å], while the coordination at the Te atom is angular [C—Te—C = 95.92 (14)°]. In the crystal structure, there are Csp—H⋯N hydrogen bonds which are perpendicular to the CNMe(2) group; the N atom displays some degree of pyramidalization. Centrosymmetrically related pairs of molecules are linked by Te⋯π(aryl) interactions, with Te⋯Cg = 3.683 (4) Å and Csp—Te⋯Cg = 159.1 (2)° (Cg is the centroid of the benzene ring). These interactions lead to the formation of zigzag ribbons which run along c and are approximately parallel to (110). |
format | Text |
id | pubmed-2968982 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29689822010-12-30 4-(Dimethylamino)phenyl ethynyl telluride Farran, Joan Alvarez-Larena, Angel Piniella, Joan F. Capparelli, Mario V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(11)NTe, is the first organyl ethynyl telluride, R—Te—C C—H, to be structurally characterized. In the L-shaped molecule, the aryl moiety, viz. Me(2)NC(6)H(4)Te, is almost perpendicular to the Te—C C—H fragment. The Te—Csp (2) bond [2.115 (3) Å] is significantly longer than the Te—Csp bond [2.041 (4) Å]. The Te—C C group is approximately linear [Te—C—C = 178.5 (4)° and C C = 1.161 (5) Å], while the coordination at the Te atom is angular [C—Te—C = 95.92 (14)°]. In the crystal structure, there are Csp—H⋯N hydrogen bonds which are perpendicular to the CNMe(2) group; the N atom displays some degree of pyramidalization. Centrosymmetrically related pairs of molecules are linked by Te⋯π(aryl) interactions, with Te⋯Cg = 3.683 (4) Å and Csp—Te⋯Cg = 159.1 (2)° (Cg is the centroid of the benzene ring). These interactions lead to the formation of zigzag ribbons which run along c and are approximately parallel to (110). International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968982/ /pubmed/21582534 http://dx.doi.org/10.1107/S1600536809009404 Text en © Farran et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Farran, Joan Alvarez-Larena, Angel Piniella, Joan F. Capparelli, Mario V. 4-(Dimethylamino)phenyl ethynyl telluride |
title | 4-(Dimethylamino)phenyl ethynyl telluride |
title_full | 4-(Dimethylamino)phenyl ethynyl telluride |
title_fullStr | 4-(Dimethylamino)phenyl ethynyl telluride |
title_full_unstemmed | 4-(Dimethylamino)phenyl ethynyl telluride |
title_short | 4-(Dimethylamino)phenyl ethynyl telluride |
title_sort | 4-(dimethylamino)phenyl ethynyl telluride |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968982/ https://www.ncbi.nlm.nih.gov/pubmed/21582534 http://dx.doi.org/10.1107/S1600536809009404 |
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