8-(Biphenyl-2-yl)-7,9-diphenyl-8H-cyclo­penta­[a]acenaphthylen-8-ol

In the title compound, C(39)H(26)O, the cyclo­penta­[a]acenaphthyl­ene skeleton displays the expected distortions, with formal sp (2) bond angles as high as C—C—C = 142.50 (10)°. The OH group forms inter­molecular hydrogen bonds via x-axis translation to the centroid (Cg) of the pendant phenyl ring...

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Detalles Bibliográficos
Autores principales: Jones, Peter G., Debeaux, Marc, Hopf, Henning, Kowalsky, Wolfgang, Johannes, Hans-Hermann
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968992/
https://www.ncbi.nlm.nih.gov/pubmed/21582628
http://dx.doi.org/10.1107/S1600536809011222
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author Jones, Peter G.
Debeaux, Marc
Hopf, Henning
Kowalsky, Wolfgang
Johannes, Hans-Hermann
author_facet Jones, Peter G.
Debeaux, Marc
Hopf, Henning
Kowalsky, Wolfgang
Johannes, Hans-Hermann
author_sort Jones, Peter G.
collection PubMed
description In the title compound, C(39)H(26)O, the cyclo­penta­[a]acenaphthyl­ene skeleton displays the expected distortions, with formal sp (2) bond angles as high as C—C—C = 142.50 (10)°. The OH group forms inter­molecular hydrogen bonds via x-axis translation to the centroid (Cg) of the pendant phenyl ring of the biphenyl system, with H⋯Cg = 2.41 Å and O—H⋯Cg = 153°.
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spelling pubmed-29689922010-12-30 8-(Biphenyl-2-yl)-7,9-diphenyl-8H-cyclo­penta­[a]acenaphthylen-8-ol Jones, Peter G. Debeaux, Marc Hopf, Henning Kowalsky, Wolfgang Johannes, Hans-Hermann Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(39)H(26)O, the cyclo­penta­[a]acenaphthyl­ene skeleton displays the expected distortions, with formal sp (2) bond angles as high as C—C—C = 142.50 (10)°. The OH group forms inter­molecular hydrogen bonds via x-axis translation to the centroid (Cg) of the pendant phenyl ring of the biphenyl system, with H⋯Cg = 2.41 Å and O—H⋯Cg = 153°. International Union of Crystallography 2009-03-31 /pmc/articles/PMC2968992/ /pubmed/21582628 http://dx.doi.org/10.1107/S1600536809011222 Text en © Jones et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jones, Peter G.
Debeaux, Marc
Hopf, Henning
Kowalsky, Wolfgang
Johannes, Hans-Hermann
8-(Biphenyl-2-yl)-7,9-diphenyl-8H-cyclo­penta­[a]acenaphthylen-8-ol
title 8-(Biphenyl-2-yl)-7,9-diphenyl-8H-cyclo­penta­[a]acenaphthylen-8-ol
title_full 8-(Biphenyl-2-yl)-7,9-diphenyl-8H-cyclo­penta­[a]acenaphthylen-8-ol
title_fullStr 8-(Biphenyl-2-yl)-7,9-diphenyl-8H-cyclo­penta­[a]acenaphthylen-8-ol
title_full_unstemmed 8-(Biphenyl-2-yl)-7,9-diphenyl-8H-cyclo­penta­[a]acenaphthylen-8-ol
title_short 8-(Biphenyl-2-yl)-7,9-diphenyl-8H-cyclo­penta­[a]acenaphthylen-8-ol
title_sort 8-(biphenyl-2-yl)-7,9-diphenyl-8h-cyclo­penta­[a]acenaphthylen-8-ol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968992/
https://www.ncbi.nlm.nih.gov/pubmed/21582628
http://dx.doi.org/10.1107/S1600536809011222
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