2,2′-Diamino-N,N′-(o-phenyl­ene)di­benz­amide

In the structure of the title compound, C(20)H(18)N(4)O(2), the N—H and C=O bonds are trans to each other and the amide O atoms are syn to the ortho amino N atom in the benzoyl rings. The amide groups form dihedral angles of 8.4 (2) and 13.8 (2)° with their respective benzoyl rings, and dihedral ang...

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Detalles Bibliográficos
Autores principales: Booysen, Irvin, Gerber, Thomas I. A., Hosten, Eric, Mayer, Peter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968993/
https://www.ncbi.nlm.nih.gov/pubmed/21582568
http://dx.doi.org/10.1107/S1600536809009283
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author Booysen, Irvin
Gerber, Thomas I. A.
Hosten, Eric
Mayer, Peter
author_facet Booysen, Irvin
Gerber, Thomas I. A.
Hosten, Eric
Mayer, Peter
author_sort Booysen, Irvin
collection PubMed
description In the structure of the title compound, C(20)H(18)N(4)O(2), the N—H and C=O bonds are trans to each other and the amide O atoms are syn to the ortho amino N atom in the benzoyl rings. The amide groups form dihedral angles of 8.4 (2) and 13.8 (2)° with their respective benzoyl rings, and dihedral angles of 51.85 (16) and 51.19 (17)° with the phenyl­enediamine ring. In the crystal, a centrosymmetric dimer is formed by inter­molecular N—H⋯O hydrogen bonds, resulting in an R (2) (2)(14) descriptor on a unitary level of graph-set analysis, and three intramolecular N—H⋯O bonds also occur.
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spelling pubmed-29689932010-12-30 2,2′-Diamino-N,N′-(o-phenyl­ene)di­benz­amide Booysen, Irvin Gerber, Thomas I. A. Hosten, Eric Mayer, Peter Acta Crystallogr Sect E Struct Rep Online Organic Papers In the structure of the title compound, C(20)H(18)N(4)O(2), the N—H and C=O bonds are trans to each other and the amide O atoms are syn to the ortho amino N atom in the benzoyl rings. The amide groups form dihedral angles of 8.4 (2) and 13.8 (2)° with their respective benzoyl rings, and dihedral angles of 51.85 (16) and 51.19 (17)° with the phenyl­enediamine ring. In the crystal, a centrosymmetric dimer is formed by inter­molecular N—H⋯O hydrogen bonds, resulting in an R (2) (2)(14) descriptor on a unitary level of graph-set analysis, and three intramolecular N—H⋯O bonds also occur. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968993/ /pubmed/21582568 http://dx.doi.org/10.1107/S1600536809009283 Text en © Booysen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Booysen, Irvin
Gerber, Thomas I. A.
Hosten, Eric
Mayer, Peter
2,2′-Diamino-N,N′-(o-phenyl­ene)di­benz­amide
title 2,2′-Diamino-N,N′-(o-phenyl­ene)di­benz­amide
title_full 2,2′-Diamino-N,N′-(o-phenyl­ene)di­benz­amide
title_fullStr 2,2′-Diamino-N,N′-(o-phenyl­ene)di­benz­amide
title_full_unstemmed 2,2′-Diamino-N,N′-(o-phenyl­ene)di­benz­amide
title_short 2,2′-Diamino-N,N′-(o-phenyl­ene)di­benz­amide
title_sort 2,2′-diamino-n,n′-(o-phenyl­ene)di­benz­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968993/
https://www.ncbi.nlm.nih.gov/pubmed/21582568
http://dx.doi.org/10.1107/S1600536809009283
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AT gerberthomasia 22diaminonnophenylenedibenzamide
AT hosteneric 22diaminonnophenylenedibenzamide
AT mayerpeter 22diaminonnophenylenedibenzamide

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