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Diaquabis[5-(5-carboxy-2-pyridyl)tetrazolato-κ(2) N (1),N (5)]cadmium(II) dihydrate
In the title complex, [Cd(C(7)H(4)N(5)O(2))(2)(H(2)O)(2)]·2H(2)O, the water-coordinated Cd(II) atom ([Image: see text] symmetry) is coordinated by four N atoms from two symmetry-related 3-carboxypyidyl-6-tetrazolato ligands, forming a distorted octahedral complex. The uncoordinated water molecul...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968998/ https://www.ncbi.nlm.nih.gov/pubmed/21582330 http://dx.doi.org/10.1107/S1600536809007399 |
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author | Yin, Haoyong Wang, Ling Nie, Qiulin |
author_facet | Yin, Haoyong Wang, Ling Nie, Qiulin |
author_sort | Yin, Haoyong |
collection | PubMed |
description | In the title complex, [Cd(C(7)H(4)N(5)O(2))(2)(H(2)O)(2)]·2H(2)O, the water-coordinated Cd(II) atom ([Image: see text] symmetry) is coordinated by four N atoms from two symmetry-related 3-carboxypyidyl-6-tetrazolato ligands, forming a distorted octahedral complex. The uncoordinated water molecules connect the mononuclear units into a layer structure through O—H⋯N and O—H⋯O hydrogen bonds; similar hydrogen bonds between coordinated water molecules and anionic groups result in a three-dimensional structure. |
format | Text |
id | pubmed-2968998 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29689982010-12-30 Diaquabis[5-(5-carboxy-2-pyridyl)tetrazolato-κ(2) N (1),N (5)]cadmium(II) dihydrate Yin, Haoyong Wang, Ling Nie, Qiulin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(C(7)H(4)N(5)O(2))(2)(H(2)O)(2)]·2H(2)O, the water-coordinated Cd(II) atom ([Image: see text] symmetry) is coordinated by four N atoms from two symmetry-related 3-carboxypyidyl-6-tetrazolato ligands, forming a distorted octahedral complex. The uncoordinated water molecules connect the mononuclear units into a layer structure through O—H⋯N and O—H⋯O hydrogen bonds; similar hydrogen bonds between coordinated water molecules and anionic groups result in a three-dimensional structure. International Union of Crystallography 2009-03-11 /pmc/articles/PMC2968998/ /pubmed/21582330 http://dx.doi.org/10.1107/S1600536809007399 Text en © Yin et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yin, Haoyong Wang, Ling Nie, Qiulin Diaquabis[5-(5-carboxy-2-pyridyl)tetrazolato-κ(2) N (1),N (5)]cadmium(II) dihydrate |
title | Diaquabis[5-(5-carboxy-2-pyridyl)tetrazolato-κ(2)
N
(1),N
(5)]cadmium(II) dihydrate |
title_full | Diaquabis[5-(5-carboxy-2-pyridyl)tetrazolato-κ(2)
N
(1),N
(5)]cadmium(II) dihydrate |
title_fullStr | Diaquabis[5-(5-carboxy-2-pyridyl)tetrazolato-κ(2)
N
(1),N
(5)]cadmium(II) dihydrate |
title_full_unstemmed | Diaquabis[5-(5-carboxy-2-pyridyl)tetrazolato-κ(2)
N
(1),N
(5)]cadmium(II) dihydrate |
title_short | Diaquabis[5-(5-carboxy-2-pyridyl)tetrazolato-κ(2)
N
(1),N
(5)]cadmium(II) dihydrate |
title_sort | diaquabis[5-(5-carboxy-2-pyridyl)tetrazolato-κ(2)
n
(1),n
(5)]cadmium(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968998/ https://www.ncbi.nlm.nih.gov/pubmed/21582330 http://dx.doi.org/10.1107/S1600536809007399 |
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