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(3-Carb­oxy-5-sulfonatobenzoato-κ(2) O (1),O (1′))bis­[2-(2-pyrid­yl)-1H-benzimidazole-κ(2) N (2),N (3)]zinc(II) monohydrate

In the title compound, [Zn(C(8)H(4)O(7)S)(C(12)H(9)N(3))(2)]·H(2)O, the Zn(II) atom has a distorted octa­hedral coordination geometry, defined by four N atoms from two 2-(2-pyrid­yl)-1H-benzimidazole ligands and two O atoms from a deprotonated carboxyl­ate group of the 3-carb­oxy-5-sulfonatobenzoate...

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Detalles Bibliográficos
Autores principales: Chen, Li-Juan, Lin, Shen, Yang, Ming-Xing, Wu, Xiao-Yuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968999/
https://www.ncbi.nlm.nih.gov/pubmed/21582356
http://dx.doi.org/10.1107/S1600536809009180
Descripción
Sumario:In the title compound, [Zn(C(8)H(4)O(7)S)(C(12)H(9)N(3))(2)]·H(2)O, the Zn(II) atom has a distorted octa­hedral coordination geometry, defined by four N atoms from two 2-(2-pyrid­yl)-1H-benzimidazole ligands and two O atoms from a deprotonated carboxyl­ate group of the 3-carb­oxy-5-sulfonatobenzoate ligand. In the crystal structure, the complex mol­ecules are linked into a three-dimensional network by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds, and π–π stacking inter­actions with centroid–centroid separations of 3.758 (2) and 3.597 (1) Å.