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(3-Carboxy-5-sulfonatobenzoato-κ(2) O (1),O (1′))bis[2-(2-pyridyl)-1H-benzimidazole-κ(2) N (2),N (3)]zinc(II) monohydrate
In the title compound, [Zn(C(8)H(4)O(7)S)(C(12)H(9)N(3))(2)]·H(2)O, the Zn(II) atom has a distorted octahedral coordination geometry, defined by four N atoms from two 2-(2-pyridyl)-1H-benzimidazole ligands and two O atoms from a deprotonated carboxylate group of the 3-carboxy-5-sulfonatobenzoate...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968999/ https://www.ncbi.nlm.nih.gov/pubmed/21582356 http://dx.doi.org/10.1107/S1600536809009180 |
| _version_ | 1782190033603657728 |
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| author | Chen, Li-Juan Lin, Shen Yang, Ming-Xing Wu, Xiao-Yuan |
| author_facet | Chen, Li-Juan Lin, Shen Yang, Ming-Xing Wu, Xiao-Yuan |
| author_sort | Chen, Li-Juan |
| collection | PubMed |
| description | In the title compound, [Zn(C(8)H(4)O(7)S)(C(12)H(9)N(3))(2)]·H(2)O, the Zn(II) atom has a distorted octahedral coordination geometry, defined by four N atoms from two 2-(2-pyridyl)-1H-benzimidazole ligands and two O atoms from a deprotonated carboxylate group of the 3-carboxy-5-sulfonatobenzoate ligand. In the crystal structure, the complex molecules are linked into a three-dimensional network by intermolecular O—H⋯O and N—H⋯O hydrogen bonds, and π–π stacking interactions with centroid–centroid separations of 3.758 (2) and 3.597 (1) Å. |
| format | Text |
| id | pubmed-2968999 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29689992010-12-30 (3-Carboxy-5-sulfonatobenzoato-κ(2) O (1),O (1′))bis[2-(2-pyridyl)-1H-benzimidazole-κ(2) N (2),N (3)]zinc(II) monohydrate Chen, Li-Juan Lin, Shen Yang, Ming-Xing Wu, Xiao-Yuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(8)H(4)O(7)S)(C(12)H(9)N(3))(2)]·H(2)O, the Zn(II) atom has a distorted octahedral coordination geometry, defined by four N atoms from two 2-(2-pyridyl)-1H-benzimidazole ligands and two O atoms from a deprotonated carboxylate group of the 3-carboxy-5-sulfonatobenzoate ligand. In the crystal structure, the complex molecules are linked into a three-dimensional network by intermolecular O—H⋯O and N—H⋯O hydrogen bonds, and π–π stacking interactions with centroid–centroid separations of 3.758 (2) and 3.597 (1) Å. International Union of Crystallography 2009-03-19 /pmc/articles/PMC2968999/ /pubmed/21582356 http://dx.doi.org/10.1107/S1600536809009180 Text en © Chen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chen, Li-Juan Lin, Shen Yang, Ming-Xing Wu, Xiao-Yuan (3-Carboxy-5-sulfonatobenzoato-κ(2) O (1),O (1′))bis[2-(2-pyridyl)-1H-benzimidazole-κ(2) N (2),N (3)]zinc(II) monohydrate |
| title | (3-Carboxy-5-sulfonatobenzoato-κ(2)
O
(1),O
(1′))bis[2-(2-pyridyl)-1H-benzimidazole-κ(2)
N
(2),N
(3)]zinc(II) monohydrate |
| title_full | (3-Carboxy-5-sulfonatobenzoato-κ(2)
O
(1),O
(1′))bis[2-(2-pyridyl)-1H-benzimidazole-κ(2)
N
(2),N
(3)]zinc(II) monohydrate |
| title_fullStr | (3-Carboxy-5-sulfonatobenzoato-κ(2)
O
(1),O
(1′))bis[2-(2-pyridyl)-1H-benzimidazole-κ(2)
N
(2),N
(3)]zinc(II) monohydrate |
| title_full_unstemmed | (3-Carboxy-5-sulfonatobenzoato-κ(2)
O
(1),O
(1′))bis[2-(2-pyridyl)-1H-benzimidazole-κ(2)
N
(2),N
(3)]zinc(II) monohydrate |
| title_short | (3-Carboxy-5-sulfonatobenzoato-κ(2)
O
(1),O
(1′))bis[2-(2-pyridyl)-1H-benzimidazole-κ(2)
N
(2),N
(3)]zinc(II) monohydrate |
| title_sort | (3-carboxy-5-sulfonatobenzoato-κ(2)
o
(1),o
(1′))bis[2-(2-pyridyl)-1h-benzimidazole-κ(2)
n
(2),n
(3)]zinc(ii) monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968999/ https://www.ncbi.nlm.nih.gov/pubmed/21582356 http://dx.doi.org/10.1107/S1600536809009180 |
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