Cargando…

2-(4,5-Dihydro-1H-imidazol-2-yl)­pyridine

In the mol­ecule of the title compound, C(8)H(9)N(3), a new imidazoline derivative, the six- and five-membered rings are slightly twisted away from each other, forming a dihedral angle of 7.96 (15)°. In the crystal structure, neighbouring mol­ecules are linked together by inter­molecular N—H⋯N hydro...

Descripción completa

Detalles Bibliográficos
Autores principales: Kia, Reza, Fun, Hoong-Kun, Kargar, Hadi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969000/
https://www.ncbi.nlm.nih.gov/pubmed/21582505
http://dx.doi.org/10.1107/S1600536809009131
_version_ 1782190033926619136
author Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
author_facet Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
author_sort Kia, Reza
collection PubMed
description In the mol­ecule of the title compound, C(8)H(9)N(3), a new imidazoline derivative, the six- and five-membered rings are slightly twisted away from each other, forming a dihedral angle of 7.96 (15)°. In the crystal structure, neighbouring mol­ecules are linked together by inter­molecular N—H⋯N hydrogen bonds into extended one-dimensional chains along the a axis. The pyridine N atom is in close proximity to a carbon-bound H atom of the imidazoline ring, with an H⋯N distance of 2.70 Å, which is slightly shorter than the sum of the van der Waals radii of these atoms (2.75 Å). The crystal structure is further stabilized by inter­molecular C—H⋯π and π–π inter­actions (centroid-to-centroid distance 3.853 Å).
format Text
id pubmed-2969000
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29690002010-12-30 2-(4,5-Dihydro-1H-imidazol-2-yl)­pyridine Kia, Reza Fun, Hoong-Kun Kargar, Hadi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(8)H(9)N(3), a new imidazoline derivative, the six- and five-membered rings are slightly twisted away from each other, forming a dihedral angle of 7.96 (15)°. In the crystal structure, neighbouring mol­ecules are linked together by inter­molecular N—H⋯N hydrogen bonds into extended one-dimensional chains along the a axis. The pyridine N atom is in close proximity to a carbon-bound H atom of the imidazoline ring, with an H⋯N distance of 2.70 Å, which is slightly shorter than the sum of the van der Waals radii of these atoms (2.75 Å). The crystal structure is further stabilized by inter­molecular C—H⋯π and π–π inter­actions (centroid-to-centroid distance 3.853 Å). International Union of Crystallography 2009-03-19 /pmc/articles/PMC2969000/ /pubmed/21582505 http://dx.doi.org/10.1107/S1600536809009131 Text en © Kia et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
2-(4,5-Dihydro-1H-imidazol-2-yl)­pyridine
title 2-(4,5-Dihydro-1H-imidazol-2-yl)­pyridine
title_full 2-(4,5-Dihydro-1H-imidazol-2-yl)­pyridine
title_fullStr 2-(4,5-Dihydro-1H-imidazol-2-yl)­pyridine
title_full_unstemmed 2-(4,5-Dihydro-1H-imidazol-2-yl)­pyridine
title_short 2-(4,5-Dihydro-1H-imidazol-2-yl)­pyridine
title_sort 2-(4,5-dihydro-1h-imidazol-2-yl)­pyridine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969000/
https://www.ncbi.nlm.nih.gov/pubmed/21582505
http://dx.doi.org/10.1107/S1600536809009131
work_keys_str_mv AT kiareza 245dihydro1himidazol2ylpyridine
AT funhoongkun 245dihydro1himidazol2ylpyridine
AT kargarhadi 245dihydro1himidazol2ylpyridine