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2-(4,5-Dihydro-1H-imidazol-2-yl)pyridine
In the molecule of the title compound, C(8)H(9)N(3), a new imidazoline derivative, the six- and five-membered rings are slightly twisted away from each other, forming a dihedral angle of 7.96 (15)°. In the crystal structure, neighbouring molecules are linked together by intermolecular N—H⋯N hydro...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969000/ https://www.ncbi.nlm.nih.gov/pubmed/21582505 http://dx.doi.org/10.1107/S1600536809009131 |
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author | Kia, Reza Fun, Hoong-Kun Kargar, Hadi |
author_facet | Kia, Reza Fun, Hoong-Kun Kargar, Hadi |
author_sort | Kia, Reza |
collection | PubMed |
description | In the molecule of the title compound, C(8)H(9)N(3), a new imidazoline derivative, the six- and five-membered rings are slightly twisted away from each other, forming a dihedral angle of 7.96 (15)°. In the crystal structure, neighbouring molecules are linked together by intermolecular N—H⋯N hydrogen bonds into extended one-dimensional chains along the a axis. The pyridine N atom is in close proximity to a carbon-bound H atom of the imidazoline ring, with an H⋯N distance of 2.70 Å, which is slightly shorter than the sum of the van der Waals radii of these atoms (2.75 Å). The crystal structure is further stabilized by intermolecular C—H⋯π and π–π interactions (centroid-to-centroid distance 3.853 Å). |
format | Text |
id | pubmed-2969000 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29690002010-12-30 2-(4,5-Dihydro-1H-imidazol-2-yl)pyridine Kia, Reza Fun, Hoong-Kun Kargar, Hadi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(8)H(9)N(3), a new imidazoline derivative, the six- and five-membered rings are slightly twisted away from each other, forming a dihedral angle of 7.96 (15)°. In the crystal structure, neighbouring molecules are linked together by intermolecular N—H⋯N hydrogen bonds into extended one-dimensional chains along the a axis. The pyridine N atom is in close proximity to a carbon-bound H atom of the imidazoline ring, with an H⋯N distance of 2.70 Å, which is slightly shorter than the sum of the van der Waals radii of these atoms (2.75 Å). The crystal structure is further stabilized by intermolecular C—H⋯π and π–π interactions (centroid-to-centroid distance 3.853 Å). International Union of Crystallography 2009-03-19 /pmc/articles/PMC2969000/ /pubmed/21582505 http://dx.doi.org/10.1107/S1600536809009131 Text en © Kia et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kia, Reza Fun, Hoong-Kun Kargar, Hadi 2-(4,5-Dihydro-1H-imidazol-2-yl)pyridine |
title | 2-(4,5-Dihydro-1H-imidazol-2-yl)pyridine |
title_full | 2-(4,5-Dihydro-1H-imidazol-2-yl)pyridine |
title_fullStr | 2-(4,5-Dihydro-1H-imidazol-2-yl)pyridine |
title_full_unstemmed | 2-(4,5-Dihydro-1H-imidazol-2-yl)pyridine |
title_short | 2-(4,5-Dihydro-1H-imidazol-2-yl)pyridine |
title_sort | 2-(4,5-dihydro-1h-imidazol-2-yl)pyridine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969000/ https://www.ncbi.nlm.nih.gov/pubmed/21582505 http://dx.doi.org/10.1107/S1600536809009131 |
work_keys_str_mv | AT kiareza 245dihydro1himidazol2ylpyridine AT funhoongkun 245dihydro1himidazol2ylpyridine AT kargarhadi 245dihydro1himidazol2ylpyridine |