catena-Poly[[bis­(N-ethyl­ethylene­di­amine-κ(2) N,N′)copper(II)]-μ-cyanido-κ(2) N:C-[dicyanido-κ(2) C-palladium(II)]-μ-cyanido-κ(2) C:N]

The title compound, [CuPd(CN)(4)(C(4)H(12)N(2))(2)](n), consists of one-dimensional chains. The Cu and Pd atoms are both located on centers of symmetry in an alternating array of [Cu(N-Eten)(2)](2+) (N-Eten = N-ethyl­ethylenediamine) and [Pd(CN)(4)](2−) units. The Pd—C distances of 1.991 (3) and 1.9...

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Detalles Bibliográficos
Autores principales: Akitsu, Takashiro, Endo, Yuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969003/
https://www.ncbi.nlm.nih.gov/pubmed/21582351
http://dx.doi.org/10.1107/S160053680900885X
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author Akitsu, Takashiro
Endo, Yuki
author_facet Akitsu, Takashiro
Endo, Yuki
author_sort Akitsu, Takashiro
collection PubMed
description The title compound, [CuPd(CN)(4)(C(4)H(12)N(2))(2)](n), consists of one-dimensional chains. The Cu and Pd atoms are both located on centers of symmetry in an alternating array of [Cu(N-Eten)(2)](2+) (N-Eten = N-ethyl­ethylenediamine) and [Pd(CN)(4)](2−) units. The Pd—C distances of 1.991 (3) and 1.992 (3) Å are inter­mediate values compared with the analogous Ni(II) and Pt(II) complexes [Akitsu & Einaga (2007 ▶). Inorg. Chim. Acta, 360, 497–505]. Due to Jahn–Teller effects, the axial Cu—N bond distance of 2.548 (2) Å is noticeably longer than the equatorial distances [Cu—NH(2) = 2.007 (2) and Cu—NHC(2)H(5) = 2.050 (2) Å]. There are interchain hybrogen bonds, with N(—H)⋯N = 3.099(4) Å.
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spelling pubmed-29690032010-12-30 catena-Poly[[bis­(N-ethyl­ethylene­di­amine-κ(2) N,N′)copper(II)]-μ-cyanido-κ(2) N:C-[dicyanido-κ(2) C-palladium(II)]-μ-cyanido-κ(2) C:N] Akitsu, Takashiro Endo, Yuki Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [CuPd(CN)(4)(C(4)H(12)N(2))(2)](n), consists of one-dimensional chains. The Cu and Pd atoms are both located on centers of symmetry in an alternating array of [Cu(N-Eten)(2)](2+) (N-Eten = N-ethyl­ethylenediamine) and [Pd(CN)(4)](2−) units. The Pd—C distances of 1.991 (3) and 1.992 (3) Å are inter­mediate values compared with the analogous Ni(II) and Pt(II) complexes [Akitsu & Einaga (2007 ▶). Inorg. Chim. Acta, 360, 497–505]. Due to Jahn–Teller effects, the axial Cu—N bond distance of 2.548 (2) Å is noticeably longer than the equatorial distances [Cu—NH(2) = 2.007 (2) and Cu—NHC(2)H(5) = 2.050 (2) Å]. There are interchain hybrogen bonds, with N(—H)⋯N = 3.099(4) Å. International Union of Crystallography 2009-03-19 /pmc/articles/PMC2969003/ /pubmed/21582351 http://dx.doi.org/10.1107/S160053680900885X Text en © Akitsu and Endo 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Akitsu, Takashiro
Endo, Yuki
catena-Poly[[bis­(N-ethyl­ethylene­di­amine-κ(2) N,N′)copper(II)]-μ-cyanido-κ(2) N:C-[dicyanido-κ(2) C-palladium(II)]-μ-cyanido-κ(2) C:N]
title catena-Poly[[bis­(N-ethyl­ethylene­di­amine-κ(2) N,N′)copper(II)]-μ-cyanido-κ(2) N:C-[dicyanido-κ(2) C-palladium(II)]-μ-cyanido-κ(2) C:N]
title_full catena-Poly[[bis­(N-ethyl­ethylene­di­amine-κ(2) N,N′)copper(II)]-μ-cyanido-κ(2) N:C-[dicyanido-κ(2) C-palladium(II)]-μ-cyanido-κ(2) C:N]
title_fullStr catena-Poly[[bis­(N-ethyl­ethylene­di­amine-κ(2) N,N′)copper(II)]-μ-cyanido-κ(2) N:C-[dicyanido-κ(2) C-palladium(II)]-μ-cyanido-κ(2) C:N]
title_full_unstemmed catena-Poly[[bis­(N-ethyl­ethylene­di­amine-κ(2) N,N′)copper(II)]-μ-cyanido-κ(2) N:C-[dicyanido-κ(2) C-palladium(II)]-μ-cyanido-κ(2) C:N]
title_short catena-Poly[[bis­(N-ethyl­ethylene­di­amine-κ(2) N,N′)copper(II)]-μ-cyanido-κ(2) N:C-[dicyanido-κ(2) C-palladium(II)]-μ-cyanido-κ(2) C:N]
title_sort catena-poly[[bis­(n-ethyl­ethylene­di­amine-κ(2) n,n′)copper(ii)]-μ-cyanido-κ(2) n:c-[dicyanido-κ(2) c-palladium(ii)]-μ-cyanido-κ(2) c:n]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969003/
https://www.ncbi.nlm.nih.gov/pubmed/21582351
http://dx.doi.org/10.1107/S160053680900885X
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AT endoyuki catenapolybisnethylethylenediaminek2nncopperiimcyanidok2ncdicyanidok2cpalladiumiimcyanidok2cn

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