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Tris(3,5-dimethyl-1H-pyrazole-κN (2))(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cobalt(II) monohydrate
The reaction of Co(NO(3))(2)·3H(2)O with pyridine-2,6-dicarboxylic acid and 3,5-dimethyl-1H-pyrazole in a 1:1:3 molar ratio affords the title complex, [Co(C(7)H(3)NO(4))(C(5)H(8)N(2))(3)]·H(2)O. The Co(II) atom is coordinated by one pyridine-2,6-dicarboxylate chelating ligand and three 3,5-dimethyl...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969004/ https://www.ncbi.nlm.nih.gov/pubmed/21582386 http://dx.doi.org/10.1107/S1600536809010538 |
| _version_ | 1782190035068518400 |
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| author | Lin, Kun-Hua Yu, Zhe-Yin Zhong, Yan-Hua Shao, Min |
| author_facet | Lin, Kun-Hua Yu, Zhe-Yin Zhong, Yan-Hua Shao, Min |
| author_sort | Lin, Kun-Hua |
| collection | PubMed |
| description | The reaction of Co(NO(3))(2)·3H(2)O with pyridine-2,6-dicarboxylic acid and 3,5-dimethyl-1H-pyrazole in a 1:1:3 molar ratio affords the title complex, [Co(C(7)H(3)NO(4))(C(5)H(8)N(2))(3)]·H(2)O. The Co(II) atom is coordinated by one pyridine-2,6-dicarboxylate chelating ligand and three 3,5-dimethyl-1H-pyrazole ligands in a distorted octahedral geometry. Hydrogen-bonding interactions involving the coordinated carboxylate group, 3,5-dimethyl-1H-pyrazole and water help to consolidate the crystal structure |
| format | Text |
| id | pubmed-2969004 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29690042010-12-30 Tris(3,5-dimethyl-1H-pyrazole-κN (2))(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cobalt(II) monohydrate Lin, Kun-Hua Yu, Zhe-Yin Zhong, Yan-Hua Shao, Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of Co(NO(3))(2)·3H(2)O with pyridine-2,6-dicarboxylic acid and 3,5-dimethyl-1H-pyrazole in a 1:1:3 molar ratio affords the title complex, [Co(C(7)H(3)NO(4))(C(5)H(8)N(2))(3)]·H(2)O. The Co(II) atom is coordinated by one pyridine-2,6-dicarboxylate chelating ligand and three 3,5-dimethyl-1H-pyrazole ligands in a distorted octahedral geometry. Hydrogen-bonding interactions involving the coordinated carboxylate group, 3,5-dimethyl-1H-pyrazole and water help to consolidate the crystal structure International Union of Crystallography 2009-03-28 /pmc/articles/PMC2969004/ /pubmed/21582386 http://dx.doi.org/10.1107/S1600536809010538 Text en © Lin et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lin, Kun-Hua Yu, Zhe-Yin Zhong, Yan-Hua Shao, Min Tris(3,5-dimethyl-1H-pyrazole-κN (2))(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cobalt(II) monohydrate |
| title | Tris(3,5-dimethyl-1H-pyrazole-κN
(2))(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cobalt(II) monohydrate |
| title_full | Tris(3,5-dimethyl-1H-pyrazole-κN
(2))(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cobalt(II) monohydrate |
| title_fullStr | Tris(3,5-dimethyl-1H-pyrazole-κN
(2))(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cobalt(II) monohydrate |
| title_full_unstemmed | Tris(3,5-dimethyl-1H-pyrazole-κN
(2))(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cobalt(II) monohydrate |
| title_short | Tris(3,5-dimethyl-1H-pyrazole-κN
(2))(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cobalt(II) monohydrate |
| title_sort | tris(3,5-dimethyl-1h-pyrazole-κn
(2))(pyridine-2,6-dicarboxylato-κ(3)
o
(2),n,o
(6))cobalt(ii) monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969004/ https://www.ncbi.nlm.nih.gov/pubmed/21582386 http://dx.doi.org/10.1107/S1600536809010538 |
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