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1,3-Bis(2-ethoxyphenyl)triazene
The title compound, C(16)H(19)N(3)O(2), exhibits a trans geometry about the N=N double bond in the triazene unit in the solid state, and individual molecules are close to planar with r.m.s. deviations from planarity of 0.065 Å and 0.242 Å for the two independent molecules in the asymmetric unit. Di...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969009/ https://www.ncbi.nlm.nih.gov/pubmed/21582455 http://dx.doi.org/10.1107/S1600536809008034 |
Sumario: | The title compound, C(16)H(19)N(3)O(2), exhibits a trans geometry about the N=N double bond in the triazene unit in the solid state, and individual molecules are close to planar with r.m.s. deviations from planarity of 0.065 Å and 0.242 Å for the two independent molecules in the asymmetric unit. Distinct intermolecular N—H⋯N hydrogen bonds lead to the formation of dimers with an R (2) (2)(8) graph-set motif. The steric demands of the ethoxy groups in the ortho position prevent a coplanar arrangement of the two molecules in the dimers and these instead consist of two interlocked molecules that are related by a non-crystallographic pseudo-twofold rotation axis. Weak C—H⋯π interactions between the CH groups and the aromatic phenyl rings also occur. |
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