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1,3-Bis(2-ethoxy­phen­yl)triazene

The title compound, C(16)H(19)N(3)O(2), exhibits a trans geometry about the N=N double bond in the triazene unit in the solid state, and individual mol­ecules are close to planar with r.m.s. deviations from planarity of 0.065 Å and 0.242 Å for the two independent molecules in the asymmetric unit. Di...

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Detalles Bibliográficos
Autores principales: Rofouei, Mohammad Kazem, Melardi, Mohammad Reza, Salemi, Yasaman, Kazemi, Saba Razi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969009/
https://www.ncbi.nlm.nih.gov/pubmed/21582455
http://dx.doi.org/10.1107/S1600536809008034
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author Rofouei, Mohammad Kazem
Melardi, Mohammad Reza
Salemi, Yasaman
Kazemi, Saba Razi
author_facet Rofouei, Mohammad Kazem
Melardi, Mohammad Reza
Salemi, Yasaman
Kazemi, Saba Razi
author_sort Rofouei, Mohammad Kazem
collection PubMed
description The title compound, C(16)H(19)N(3)O(2), exhibits a trans geometry about the N=N double bond in the triazene unit in the solid state, and individual mol­ecules are close to planar with r.m.s. deviations from planarity of 0.065 Å and 0.242 Å for the two independent molecules in the asymmetric unit. Distinct inter­molecular N—H⋯N hydrogen bonds lead to the formation of dimers with an R (2) (2)(8) graph-set motif. The steric demands of the eth­oxy groups in the ortho position prevent a coplanar arrangement of the two mol­ecules in the dimers and these instead consist of two inter­locked mol­ecules that are related by a non-crystallographic pseudo-twofold rotation axis. Weak C—H⋯π inter­actions between the CH groups and the aromatic phenyl rings also occur.
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spelling pubmed-29690092010-12-30 1,3-Bis(2-ethoxy­phen­yl)triazene Rofouei, Mohammad Kazem Melardi, Mohammad Reza Salemi, Yasaman Kazemi, Saba Razi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(19)N(3)O(2), exhibits a trans geometry about the N=N double bond in the triazene unit in the solid state, and individual mol­ecules are close to planar with r.m.s. deviations from planarity of 0.065 Å and 0.242 Å for the two independent molecules in the asymmetric unit. Distinct inter­molecular N—H⋯N hydrogen bonds lead to the formation of dimers with an R (2) (2)(8) graph-set motif. The steric demands of the eth­oxy groups in the ortho position prevent a coplanar arrangement of the two mol­ecules in the dimers and these instead consist of two inter­locked mol­ecules that are related by a non-crystallographic pseudo-twofold rotation axis. Weak C—H⋯π inter­actions between the CH groups and the aromatic phenyl rings also occur. International Union of Crystallography 2009-03-11 /pmc/articles/PMC2969009/ /pubmed/21582455 http://dx.doi.org/10.1107/S1600536809008034 Text en © Rofouei et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rofouei, Mohammad Kazem
Melardi, Mohammad Reza
Salemi, Yasaman
Kazemi, Saba Razi
1,3-Bis(2-ethoxy­phen­yl)triazene
title 1,3-Bis(2-ethoxy­phen­yl)triazene
title_full 1,3-Bis(2-ethoxy­phen­yl)triazene
title_fullStr 1,3-Bis(2-ethoxy­phen­yl)triazene
title_full_unstemmed 1,3-Bis(2-ethoxy­phen­yl)triazene
title_short 1,3-Bis(2-ethoxy­phen­yl)triazene
title_sort 1,3-bis(2-ethoxy­phen­yl)triazene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969009/
https://www.ncbi.nlm.nih.gov/pubmed/21582455
http://dx.doi.org/10.1107/S1600536809008034
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