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(μ-3,4-Diacetylhexa-2,4-diene-2,5-diolato-κ(4) O (2),O (3):O (4),O (5))bis[aqua(1,10-phenanthroline-κ(2) N,N′)copper(II)] bis(tetrafluoridoborate) monohydrate
In the title compound, [Cu(2)(C(10)H(12)O(4))(C(12)H(8)N(2))(2)(H(2)O)(2)](BF(4))(2)·H(2)O, the two Cu atoms are each chelated by the acetylacetonate unit of the 3,4-diacetylhexa-2,4-diene-2,5-diolate (tae) ligand. The Cu atoms are square-pyramidally pentacoordinated, with one bidentate 1,10-phen...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969010/ https://www.ncbi.nlm.nih.gov/pubmed/21582322 http://dx.doi.org/10.1107/S1600536809006898 |
Sumario: | In the title compound, [Cu(2)(C(10)H(12)O(4))(C(12)H(8)N(2))(2)(H(2)O)(2)](BF(4))(2)·H(2)O, the two Cu atoms are each chelated by the acetylacetonate unit of the 3,4-diacetylhexa-2,4-diene-2,5-diolate (tae) ligand. The Cu atoms are square-pyramidally pentacoordinated, with one bidentate 1,10-phenanthroline (phen) and the tae ligand basal and one water molecule apical. The pyridyl rings of the phen ligands participate in π–π [centroid–centroid distance = 3.894 (3) Å] and C—H ⋯ π interactions, generating layers which are interconnected through O—H⋯O and O—H⋯F hydrogen bonds between the water molecules and the tetrafluoridoborate anions. The F atoms of both tetrafluoridoborate anions are each disordered over two positions of equal occupancy. |
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