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(μ-3,4-Diacetyl­hexa-2,4-diene-2,5-diol­ato-κ(4) O (2),O (3):O (4),O (5))bis­[aqua(1,10-phen­an­thro­line-κ(2) N,N′)copper(II)] bis­(tetra­fluorid­oborate) monohydrate

In the title compound, [Cu(2)(C(10)H(12)O(4))(C(12)H(8)N(2))(2)(H(2)O)(2)](BF(4))(2)·H(2)O, the two Cu atoms are each chelated by the acetyl­acetonate unit of the 3,4-diacetyl­hexa-2,4-diene-2,5-diolate (tae) ligand. The Cu atoms are square-pyramidally penta­coordinated, with one bidentate 1,10-phen...

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Detalles Bibliográficos
Autores principales: Tovilla, Jorge A., Hernández-Ortega, Simón, Valdés-Martínez, Jesús
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969010/
https://www.ncbi.nlm.nih.gov/pubmed/21582322
http://dx.doi.org/10.1107/S1600536809006898
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author Tovilla, Jorge A.
Hernández-Ortega, Simón
Valdés-Martínez, Jesús
author_facet Tovilla, Jorge A.
Hernández-Ortega, Simón
Valdés-Martínez, Jesús
author_sort Tovilla, Jorge A.
collection PubMed
description In the title compound, [Cu(2)(C(10)H(12)O(4))(C(12)H(8)N(2))(2)(H(2)O)(2)](BF(4))(2)·H(2)O, the two Cu atoms are each chelated by the acetyl­acetonate unit of the 3,4-diacetyl­hexa-2,4-diene-2,5-diolate (tae) ligand. The Cu atoms are square-pyramidally penta­coordinated, with one bidentate 1,10-phenanthroline (phen) and the tae ligand basal and one water mol­ecule apical. The pyridyl rings of the phen ligands participate in π–π [centroid–centroid distance = 3.894 (3) Å] and C—H ⋯ π inter­actions, generating layers which are inter­connected through O—H⋯O and O—H⋯F hydrogen bonds between the water mol­ecules and the tetra­fluorido­borate anions. The F atoms of both tetra­fluorido­borate anions are each disordered over two positions of equal occupancy.
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spelling pubmed-29690102010-12-30 (μ-3,4-Diacetyl­hexa-2,4-diene-2,5-diol­ato-κ(4) O (2),O (3):O (4),O (5))bis­[aqua(1,10-phen­an­thro­line-κ(2) N,N′)copper(II)] bis­(tetra­fluorid­oborate) monohydrate Tovilla, Jorge A. Hernández-Ortega, Simón Valdés-Martínez, Jesús Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(2)(C(10)H(12)O(4))(C(12)H(8)N(2))(2)(H(2)O)(2)](BF(4))(2)·H(2)O, the two Cu atoms are each chelated by the acetyl­acetonate unit of the 3,4-diacetyl­hexa-2,4-diene-2,5-diolate (tae) ligand. The Cu atoms are square-pyramidally penta­coordinated, with one bidentate 1,10-phenanthroline (phen) and the tae ligand basal and one water mol­ecule apical. The pyridyl rings of the phen ligands participate in π–π [centroid–centroid distance = 3.894 (3) Å] and C—H ⋯ π inter­actions, generating layers which are inter­connected through O—H⋯O and O—H⋯F hydrogen bonds between the water mol­ecules and the tetra­fluorido­borate anions. The F atoms of both tetra­fluorido­borate anions are each disordered over two positions of equal occupancy. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2969010/ /pubmed/21582322 http://dx.doi.org/10.1107/S1600536809006898 Text en © Tovilla et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tovilla, Jorge A.
Hernández-Ortega, Simón
Valdés-Martínez, Jesús
(μ-3,4-Diacetyl­hexa-2,4-diene-2,5-diol­ato-κ(4) O (2),O (3):O (4),O (5))bis­[aqua(1,10-phen­an­thro­line-κ(2) N,N′)copper(II)] bis­(tetra­fluorid­oborate) monohydrate
title (μ-3,4-Diacetyl­hexa-2,4-diene-2,5-diol­ato-κ(4) O (2),O (3):O (4),O (5))bis­[aqua(1,10-phen­an­thro­line-κ(2) N,N′)copper(II)] bis­(tetra­fluorid­oborate) monohydrate
title_full (μ-3,4-Diacetyl­hexa-2,4-diene-2,5-diol­ato-κ(4) O (2),O (3):O (4),O (5))bis­[aqua(1,10-phen­an­thro­line-κ(2) N,N′)copper(II)] bis­(tetra­fluorid­oborate) monohydrate
title_fullStr (μ-3,4-Diacetyl­hexa-2,4-diene-2,5-diol­ato-κ(4) O (2),O (3):O (4),O (5))bis­[aqua(1,10-phen­an­thro­line-κ(2) N,N′)copper(II)] bis­(tetra­fluorid­oborate) monohydrate
title_full_unstemmed (μ-3,4-Diacetyl­hexa-2,4-diene-2,5-diol­ato-κ(4) O (2),O (3):O (4),O (5))bis­[aqua(1,10-phen­an­thro­line-κ(2) N,N′)copper(II)] bis­(tetra­fluorid­oborate) monohydrate
title_short (μ-3,4-Diacetyl­hexa-2,4-diene-2,5-diol­ato-κ(4) O (2),O (3):O (4),O (5))bis­[aqua(1,10-phen­an­thro­line-κ(2) N,N′)copper(II)] bis­(tetra­fluorid­oborate) monohydrate
title_sort (μ-3,4-diacetyl­hexa-2,4-diene-2,5-diol­ato-κ(4) o (2),o (3):o (4),o (5))bis­[aqua(1,10-phen­an­thro­line-κ(2) n,n′)copper(ii)] bis­(tetra­fluorid­oborate) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969010/
https://www.ncbi.nlm.nih.gov/pubmed/21582322
http://dx.doi.org/10.1107/S1600536809006898
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