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(2R,5S)-5-Benzyl-2,3-dimethyl-4-oxo-2-phenyl­imidazolidin-1-ium chloride

The title hydro­chloride salt, C(18)H(21)N(2)O(+)·Cl(−), is an imidazolidinone catalyst, which was derived from L-phenyl­alanine through cyclization with acetophenone. The imidazolidinone compound has a five-membered heterocyclic ring including two chiral centres. The imidazolidinone ring displays a...

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Detalles Bibliográficos
Autores principales: Zhang, Shuai, Wang, Yifeng, Li, Bailin, Zhang, Guangcun, Luo, Shuping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969013/
https://www.ncbi.nlm.nih.gov/pubmed/21582597
http://dx.doi.org/10.1107/S1600536809010460
Descripción
Sumario:The title hydro­chloride salt, C(18)H(21)N(2)O(+)·Cl(−), is an imidazolidinone catalyst, which was derived from L-phenyl­alanine through cyclization with acetophenone. The imidazolidinone compound has a five-membered heterocyclic ring including two chiral centres. The imidazolidinone ring displays an envelope conformation, with the flap protonated N atom lying 0.497 (3) Å above the mean plane of the remaining four atoms. In the crystal structure, one-dimensional supra­molecular chains parallel to the crystallographic 2(1) screw axis are formed by N—H⋯Cl hydrogen bonds involving the NH(2) (+) and Cl(−) groups. Intra­molecular N—H⋯Cl inter­actions are also present.