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(2R,5S)-5-Benzyl-2,3-dimethyl-4-oxo-2-phenyl­imidazolidin-1-ium chloride

The title hydro­chloride salt, C(18)H(21)N(2)O(+)·Cl(−), is an imidazolidinone catalyst, which was derived from L-phenyl­alanine through cyclization with acetophenone. The imidazolidinone compound has a five-membered heterocyclic ring including two chiral centres. The imidazolidinone ring displays a...

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Detalles Bibliográficos
Autores principales: Zhang, Shuai, Wang, Yifeng, Li, Bailin, Zhang, Guangcun, Luo, Shuping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969013/
https://www.ncbi.nlm.nih.gov/pubmed/21582597
http://dx.doi.org/10.1107/S1600536809010460
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author Zhang, Shuai
Wang, Yifeng
Li, Bailin
Zhang, Guangcun
Luo, Shuping
author_facet Zhang, Shuai
Wang, Yifeng
Li, Bailin
Zhang, Guangcun
Luo, Shuping
author_sort Zhang, Shuai
collection PubMed
description The title hydro­chloride salt, C(18)H(21)N(2)O(+)·Cl(−), is an imidazolidinone catalyst, which was derived from L-phenyl­alanine through cyclization with acetophenone. The imidazolidinone compound has a five-membered heterocyclic ring including two chiral centres. The imidazolidinone ring displays an envelope conformation, with the flap protonated N atom lying 0.497 (3) Å above the mean plane of the remaining four atoms. In the crystal structure, one-dimensional supra­molecular chains parallel to the crystallographic 2(1) screw axis are formed by N—H⋯Cl hydrogen bonds involving the NH(2) (+) and Cl(−) groups. Intra­molecular N—H⋯Cl inter­actions are also present.
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spelling pubmed-29690132010-12-30 (2R,5S)-5-Benzyl-2,3-dimethyl-4-oxo-2-phenyl­imidazolidin-1-ium chloride Zhang, Shuai Wang, Yifeng Li, Bailin Zhang, Guangcun Luo, Shuping Acta Crystallogr Sect E Struct Rep Online Organic Papers The title hydro­chloride salt, C(18)H(21)N(2)O(+)·Cl(−), is an imidazolidinone catalyst, which was derived from L-phenyl­alanine through cyclization with acetophenone. The imidazolidinone compound has a five-membered heterocyclic ring including two chiral centres. The imidazolidinone ring displays an envelope conformation, with the flap protonated N atom lying 0.497 (3) Å above the mean plane of the remaining four atoms. In the crystal structure, one-dimensional supra­molecular chains parallel to the crystallographic 2(1) screw axis are formed by N—H⋯Cl hydrogen bonds involving the NH(2) (+) and Cl(−) groups. Intra­molecular N—H⋯Cl inter­actions are also present. International Union of Crystallography 2009-03-28 /pmc/articles/PMC2969013/ /pubmed/21582597 http://dx.doi.org/10.1107/S1600536809010460 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Shuai
Wang, Yifeng
Li, Bailin
Zhang, Guangcun
Luo, Shuping
(2R,5S)-5-Benzyl-2,3-dimethyl-4-oxo-2-phenyl­imidazolidin-1-ium chloride
title (2R,5S)-5-Benzyl-2,3-dimethyl-4-oxo-2-phenyl­imidazolidin-1-ium chloride
title_full (2R,5S)-5-Benzyl-2,3-dimethyl-4-oxo-2-phenyl­imidazolidin-1-ium chloride
title_fullStr (2R,5S)-5-Benzyl-2,3-dimethyl-4-oxo-2-phenyl­imidazolidin-1-ium chloride
title_full_unstemmed (2R,5S)-5-Benzyl-2,3-dimethyl-4-oxo-2-phenyl­imidazolidin-1-ium chloride
title_short (2R,5S)-5-Benzyl-2,3-dimethyl-4-oxo-2-phenyl­imidazolidin-1-ium chloride
title_sort (2r,5s)-5-benzyl-2,3-dimethyl-4-oxo-2-phenyl­imidazolidin-1-ium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969013/
https://www.ncbi.nlm.nih.gov/pubmed/21582597
http://dx.doi.org/10.1107/S1600536809010460
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