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(2R,5S)-5-Benzyl-2,3-dimethyl-4-oxo-2-phenylimidazolidin-1-ium chloride
The title hydrochloride salt, C(18)H(21)N(2)O(+)·Cl(−), is an imidazolidinone catalyst, which was derived from L-phenylalanine through cyclization with acetophenone. The imidazolidinone compound has a five-membered heterocyclic ring including two chiral centres. The imidazolidinone ring displays a...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969013/ https://www.ncbi.nlm.nih.gov/pubmed/21582597 http://dx.doi.org/10.1107/S1600536809010460 |
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author | Zhang, Shuai Wang, Yifeng Li, Bailin Zhang, Guangcun Luo, Shuping |
author_facet | Zhang, Shuai Wang, Yifeng Li, Bailin Zhang, Guangcun Luo, Shuping |
author_sort | Zhang, Shuai |
collection | PubMed |
description | The title hydrochloride salt, C(18)H(21)N(2)O(+)·Cl(−), is an imidazolidinone catalyst, which was derived from L-phenylalanine through cyclization with acetophenone. The imidazolidinone compound has a five-membered heterocyclic ring including two chiral centres. The imidazolidinone ring displays an envelope conformation, with the flap protonated N atom lying 0.497 (3) Å above the mean plane of the remaining four atoms. In the crystal structure, one-dimensional supramolecular chains parallel to the crystallographic 2(1) screw axis are formed by N—H⋯Cl hydrogen bonds involving the NH(2) (+) and Cl(−) groups. Intramolecular N—H⋯Cl interactions are also present. |
format | Text |
id | pubmed-2969013 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29690132010-12-30 (2R,5S)-5-Benzyl-2,3-dimethyl-4-oxo-2-phenylimidazolidin-1-ium chloride Zhang, Shuai Wang, Yifeng Li, Bailin Zhang, Guangcun Luo, Shuping Acta Crystallogr Sect E Struct Rep Online Organic Papers The title hydrochloride salt, C(18)H(21)N(2)O(+)·Cl(−), is an imidazolidinone catalyst, which was derived from L-phenylalanine through cyclization with acetophenone. The imidazolidinone compound has a five-membered heterocyclic ring including two chiral centres. The imidazolidinone ring displays an envelope conformation, with the flap protonated N atom lying 0.497 (3) Å above the mean plane of the remaining four atoms. In the crystal structure, one-dimensional supramolecular chains parallel to the crystallographic 2(1) screw axis are formed by N—H⋯Cl hydrogen bonds involving the NH(2) (+) and Cl(−) groups. Intramolecular N—H⋯Cl interactions are also present. International Union of Crystallography 2009-03-28 /pmc/articles/PMC2969013/ /pubmed/21582597 http://dx.doi.org/10.1107/S1600536809010460 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhang, Shuai Wang, Yifeng Li, Bailin Zhang, Guangcun Luo, Shuping (2R,5S)-5-Benzyl-2,3-dimethyl-4-oxo-2-phenylimidazolidin-1-ium chloride |
title | (2R,5S)-5-Benzyl-2,3-dimethyl-4-oxo-2-phenylimidazolidin-1-ium chloride |
title_full | (2R,5S)-5-Benzyl-2,3-dimethyl-4-oxo-2-phenylimidazolidin-1-ium chloride |
title_fullStr | (2R,5S)-5-Benzyl-2,3-dimethyl-4-oxo-2-phenylimidazolidin-1-ium chloride |
title_full_unstemmed | (2R,5S)-5-Benzyl-2,3-dimethyl-4-oxo-2-phenylimidazolidin-1-ium chloride |
title_short | (2R,5S)-5-Benzyl-2,3-dimethyl-4-oxo-2-phenylimidazolidin-1-ium chloride |
title_sort | (2r,5s)-5-benzyl-2,3-dimethyl-4-oxo-2-phenylimidazolidin-1-ium chloride |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969013/ https://www.ncbi.nlm.nih.gov/pubmed/21582597 http://dx.doi.org/10.1107/S1600536809010460 |
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