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Aqua­(dicyanamido)­{μ-6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­i­dyne)]diphenolato}copper(II)sodium(I)

The mol­ecule of the title compound, [CuNa(C(18)H(18)N(2)O(4))(C(2)N(3))(H(2)O)], is almost planar, the maximum deviation from the mol­ecular plane being 0.48 (4) Å. The coordination environment of the Cu(2+) ion is distorted square-planar and it is N (2) O (2)-chelated by the Schiff base ligand. Th...

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Detalles Bibliográficos
Autores principales: Shen, Yong-Miao, Wang, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969014/
https://www.ncbi.nlm.nih.gov/pubmed/21582402
http://dx.doi.org/10.1107/S1600536809011064
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author Shen, Yong-Miao
Wang, Wei
author_facet Shen, Yong-Miao
Wang, Wei
author_sort Shen, Yong-Miao
collection PubMed
description The mol­ecule of the title compound, [CuNa(C(18)H(18)N(2)O(4))(C(2)N(3))(H(2)O)], is almost planar, the maximum deviation from the mol­ecular plane being 0.48 (4) Å. The coordination environment of the Cu(2+) ion is distorted square-planar and it is N (2) O (2)-chelated by the Schiff base ligand. The Na(+) cation has a distorted octahedral environment defined by the four O atoms of the 6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolate ligand, a water ligand and a dicyanamide anion.
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spelling pubmed-29690142010-12-30 Aqua­(dicyanamido)­{μ-6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­i­dyne)]diphenolato}copper(II)sodium(I) Shen, Yong-Miao Wang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecule of the title compound, [CuNa(C(18)H(18)N(2)O(4))(C(2)N(3))(H(2)O)], is almost planar, the maximum deviation from the mol­ecular plane being 0.48 (4) Å. The coordination environment of the Cu(2+) ion is distorted square-planar and it is N (2) O (2)-chelated by the Schiff base ligand. The Na(+) cation has a distorted octahedral environment defined by the four O atoms of the 6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolate ligand, a water ligand and a dicyanamide anion. International Union of Crystallography 2009-03-31 /pmc/articles/PMC2969014/ /pubmed/21582402 http://dx.doi.org/10.1107/S1600536809011064 Text en © Shen and Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shen, Yong-Miao
Wang, Wei
Aqua­(dicyanamido)­{μ-6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­i­dyne)]diphenolato}copper(II)sodium(I)
title Aqua­(dicyanamido)­{μ-6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­i­dyne)]diphenolato}copper(II)sodium(I)
title_full Aqua­(dicyanamido)­{μ-6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­i­dyne)]diphenolato}copper(II)sodium(I)
title_fullStr Aqua­(dicyanamido)­{μ-6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­i­dyne)]diphenolato}copper(II)sodium(I)
title_full_unstemmed Aqua­(dicyanamido)­{μ-6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­i­dyne)]diphenolato}copper(II)sodium(I)
title_short Aqua­(dicyanamido)­{μ-6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­i­dyne)]diphenolato}copper(II)sodium(I)
title_sort aqua­(dicyanamido)­{μ-6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­i­dyne)]diphenolato}copper(ii)sodium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969014/
https://www.ncbi.nlm.nih.gov/pubmed/21582402
http://dx.doi.org/10.1107/S1600536809011064
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