Bis(benzoyl­acetonato)bis­(1,3-di-4-pyridyl­propane)manganese(II)

In the title compound, [Mn(C(10)H(9)O(2))(2)(C(13)H(14)N(2))(2)], the Mn(II) ion lies on a crystallographic inversion center and has a slightly distorted octa­hedral coordination environment. Weak π–π stacking inter­actions, with centroid–centroid distances of 3.862 (2) and 3.887 (5) Å, and signific...

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Detalles Bibliográficos
Autores principales: Zhou, Yan, Zhao, Wen-Na, Han, Lei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969015/
https://www.ncbi.nlm.nih.gov/pubmed/21582365
http://dx.doi.org/10.1107/S1600536809009891
Descripción
Sumario:In the title compound, [Mn(C(10)H(9)O(2))(2)(C(13)H(14)N(2))(2)], the Mn(II) ion lies on a crystallographic inversion center and has a slightly distorted octa­hedral coordination environment. Weak π–π stacking inter­actions, with centroid–centroid distances of 3.862 (2) and 3.887 (5) Å, and significant C—H⋯π inter­actions help to stabilize the crystal structure. The atoms of the unique terminal 4-pyridine­propane group are disordered over two sites, the ratio of refined occpancies being 0.712 (7):0.288 (7).

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